Organic synthetic routes

Cards (26)

  • Alkene → poly(alkene)

    Conditions: High pressure, catalyst
  • Alkene → dihalogenoalkane

    Reagents: Br2 or Cl2
    Conditions: Room temperature
    Mechanism: Electrophilic Addition
  • Dihalogenoalkane → diol

    Reagents: KOH(aq)
    Conditions: Heat under reflux
    Mechanism: Nucleophilic Substitution
  • Alkene → halogenoalkane

    Reagents: HBr or HCl
    Conditions: Room temperature
    Mechanism: Electrophilic Addition
  • Alkane → halogenoalkane

    Reagents: Br2 or Cl2
    Conditions: UV light
    Mechanism: Free Radical Substitution
  • Halogenoalkane → alkene

    Reagents: KOH alcoholic
    Conditions: Heat under reflux
    Mechanism: Elimination
  • Alcohol → alkene
    Reagents: Conc H2SO4 or Conc H3PO4
    Mechanism: Elimination, dehydration
  • Alkene → alcohol
    Step 1:
    Reagents: H2SO4
    Mechanism: Electrophilic Addition
    Step 2:
    Reagents: H2O warm
    Reaction: Hydrolysis
  • Halogenoalkane → alcohol

    Reagents: KOH(aq)
    Conditions: Heat under reflux
    Mechanism: Nucleophilic Substitution
  • Alcohol → aldehyde
    Reagents: K2CR2O7/H+
    Conditions: Heat and distill
    Reaction: Partial Oxidation
  • Alcohol → ketone
    Reagents: K2CR2O7/H+
    Conditions: Heat
    Reaction: Oxidation
  • Aldehyde → Carboxylic acid
    Reagents: K2CR2O7/H+
    Conditions: Heat under reflux and excess oxidising agent
    Reaction: Oxidation
  • Aldehyde/Ketone → hydroxynitrile

    Reagents: KCN and H2SO4
    Mechanism: Nucleophilic Addition
  • Aldehyde → alcohol
    Reagents: NaBH4
    Reaction: Reduction
    Mechanism: Nucleophilic Addition
  • Ketone → alcohol
    Reagents: NaBH4
    Reaction: Reduction
    Mechanism: Nucleophilic Addition
  • Carboxylic acid → ester
    Reagents: Alcohol and H2SO4
    Conditions: Heat
    Reaction: esterification
  • Alcohol → ester
    Reagents: Carboxylic acid and H2SO4
    Conditions: Heat
    Reaction: Esterification
  • Acyl chloride/Acid anhydride → carboxylic acid
    Reagents: H2O
    Conditions: Room temperature
    Mechanism: Nucleophilic addition/elimination
  • Acyl chloride/Acid anhydride → ester
    Reagents: Alcohol
    Conditions: Room temperature
    Mechanism: Nucleophilic addition/elimination
  • Acyl chloride/Acid anhydride → primary amide
    Reagents: NH3
    Conditions: Room temperature
    Mechanism: Nucleophilic addition/elimination
  • Acyl chloride/Acid anhydride → secondary amide
    Reagents: Primary amine
    Conditions: Room temperature
    Mechanism: Nucleophilic addition/elimination
  • Halogenoalkane → nitrile
    Reagents: KCN in ethanol/water
    Conditions: Heat under reflux
    Mechanism: Nucleophilic Substitution
  • Halogenoalkane → primary amine
    Reagents: Alcoholic NH3
    Conditions: Heat under pressure
    Mechanism: Nucleophilic substitution
  • Nitrile → primary amine
    Reagents: LiAlH4 in ether
    Reaction: Reduction
  • Primary amine → secondary/tertiary amine or quaternary salt
    Reagents: Halogenoalkane
    Mechanism: Nucleophilic Substitution
  • Primary amine → Secondary amine
    Reagents: Acyl chloride
    Conditions: Room temperature
    Mechanism: Nucleophilic addition/elimination