forwards and backwards reaction occurring at the same rate
what does equilibrium depend on?
temp, pressure, concentration
what is a closed system?
none of reactants of products can escape
closed system
nothing can get in
what does a reversible reaction reach?
equilibrium
Exothermic reaction
Reaction in which energy is given out to the surroundings, causing the temperature of the surroundings to increase
Endothermic reaction
Reaction in which energy is taken in from the surroundings, causing the temperature of the surroundings to decrease
Exothermic reactions
Combustion reactions
Many oxidation reactions
Most neutralisation reactions
Endothermic reactions
Thermal decomposition reactions
Reaction of citric acid and sodium hydrogencarbonate
Energy is conserved in chemical reactions, so the total amount of energy in the universe at the end of a reaction is the same as it was before the reaction
In exothermic reactions
Energy exits
In endothermic reactions
Energy enters
Everyday uses of exothermic reactions include self-heating cans and hand warmers
Everyday uses of endothermic reactions include instant ice packs which can be used to treat sports injuries
Exothermic reaction between dilute sodium hydroxide and hydrochloric acid
1. Sodium hydroxide solution is poured into a beaker of hydrochloric acid
2. The beaker now contains sodium chloride and water
3. The thermometer is showing a rise in temperature, so the neutralisation reaction is exothermic
Endothermic reaction between sodium carbonate and ethanoic acid
1. Sodium carbonate powder is tipped into a beaker of ethanoic acid
2. The beaker now contains sodium ethanoate, water and carbon dioxide
3. The thermometer is showing a fall in temperature, so this was an endothermic reaction
Hydrocarbon
A compound that contains hydrogen and carbon only
Compound
A substance formed by the chemical union of two or more elements
Atom
The smallest part of an element that can exist
Crude oil
Mixture of hydrocarbons, mainly alkanes, formed over millions of years from the remains of ancient dead marine organisms
Crude oil
It is a finite resource that is found in the Earth's crust
It is the remains of organisms that lived and died millions of years ago - mainly plankton which was buried in mud
Mixture
Two or more substances that are not joined together. The substances can be elements, compounds, or both
Hydrocarbon molecules
Chains and rings of carbon atoms with hydrogen atoms
Fuel
Material that is used to produce heat, like coal, oil or gas
Petrochemical
Substance made from crude oil using chemical reactions
Substances made from compounds in crude oil
Ethene
Poly(ethene)
Solvents
Lubricants
Detergents
Crude oil is an important source of fuels and feedstock for the petrochemical industry
Crude oil is a finite resource
Petrol and other fuels are produced from crude oil using fractional distillation
Cracking is used to convert long alkanes into shorter, more useful hydrocarbons
Alkanes
Saturated hydrocarbons - compounds containing hydrogen and carbon only, with no C=C bonds
General formula for alkanes
CnH2n+2, where n is the number of carbon atoms
Alkanes
Decane
Hexane
Covalent bonds in alkanes are not really at 90 degree angles, as shown in the structures
Alkanes are saturated hydrocarbons - they contain no carbon-to-carbon double bonds, only single bonds
Crude oil
Mixture of hydrocarbons, mainly alkanes, formed over millions of years from the remains of ancient dead marine organisms
Fractional distillation
A method used to separate a mixture of several substances, such as crude oil, into simpler, more useful mixtures by distilling and collecting the evaporated components as they condense at different temperatures
Crude oil is a finite resource
Petrol and other fuels are produced from crude oil using fractional distillation