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ORGANIC 1
ORGANIC ANALYSIS
CHEMICAL TESTS
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Jasmine Singh
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Cards (28)
KEY SUBSTANCES TO IDENTIFY?
alkene
halogenoalkane
alcohol
aldehyde
carboxylic acid
FUNCTIONAL GROUP OF AN ALKENE?
C=C
GENERAL FORMULA OF A HALOGENOALKANE?
R-X
GENERAL FORMULA OF AN ALCOHOL?
R-OH
GENERAL FORMULA OF AN ALDEHYDE?
R-CHO
GENERAL FORMULA OF A CARBOXYLIC ACID?
R-COOH
REAGENT USED TO TEST FOR AN ALKENE?
bromine water
TEST FOR ALKENES?
shake
with
bromine water
POSITIVE RESULT FOR A BROMINE WATER TEST ON AN ALKENE?
orange colour disappears
(becomes
colourless
)
REAGENTS REQUIRED TO TEST A HALOGENOALKANE?
NaOH
,
HNO3
,
AgNO3
TEST FOR HALOGENOALKANES?
Add NaOH
(
aq
) and
warm
Acidify
with
HNO3
Add AgNO3
(
aq
)
POSITIVE RESULT OF A SILVER NITRATE TEST FOR HALOGENOALKANES?
AgX precipitate
WHAT COLOUR PRECIPITATE DOES CHLORINE IONS PRODUCE?
white
WHAT COLOUR PRECIPITATE DO BROMINE IONS PRODUCE?
very pale cream
WHAT COLOUR PRECIPITATE DO IODINE IONS PRODUCE?
very pale yellow
REAGENT TO TEST FOR ALCOHOLS?
acidified K2Cr2O7
TEST FOR ALCOHOLS?
add acidified K2Cr2O7
POSITIVE RESULT FOR ACIDIFIED K2CR2O7 TEST ON ALCOHOLS?
orange colour
turns
green
WHEN WILL THE ACIDIFED K2CR2O7 TEST HAVE A POSITIVE RESULT?
primary
/
secondary alcohols
and
aldehydes
WHAT ION CAUSES THE ORANGE COLOUR OF ACIDIFED K2Cr2O7?
Cr
(
+6
)
WHAT ION CAUSES THE GREEN COLOUR OF ACIDIFED K2Cr2O7?
Cr
(
+3
)
REAGENT FOR TESTING FOR ALDEHYDES?
Fehling's solution
/
Tollens' solution
TEST FOR ALDEHYDES?
warm
with
Fehling's solution
/
Tollens' solution
POSITIVE RESULT FOR ALDEHYDE TEST (FEHLING'S SOLUTION)?
blue colour
turns to
red precipitate
POSITIVE RESULT FOR ALDEHYDE TEST (TOLLENS' SOLUTION)?
silver mirror forms
REAGENT FOR CARBOXYLIC ACID TEST?
NaHCO3
(
aq
)
TEST FOR CARBOXYLIC ACIDS?
add
NaHCO3
(
aq
)
POSITIVE RESULT FOR TEST FOR CARBOXYLIC ACID?
CO2 given off