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INORG ORG CHEM FINALS
Aromatic Compounds
NOMENCLATURE OF AROMATIC COMPOUNDS
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Structure contains two or more rings fused together
Fused Rings
2 carbon rings that share a pair of carbon are said to be
fused
Uses the name of the substituent as a prefix to the name “benzene”
Benzene Derivatives
with
One Substituent
methylbenzene
Toluene
vinylbenzene
Styrene
TOLUENE
CH3 OR METHY
PHENOL
OH OR ALCOHOL
ANILINE
NH2
OR
AMMONIA GAS
BENZOIC ACID
O=C-OH OR CARBOXYLIC ACID
BENZALDEHYDE
O=
C-H
OR
FORMYL
ANISOLE
O-CH3
OR
METHOXY
BENZENESULFONIC ACID
SO3H
OR
SULFONIC ACID
ACETOPHENONE
O=C-CH3
STYRENE
VINYL GROUP
Specify the positions of the substituents relative to one another
Benzene
Derivatives with
Two
Substituent
describes a molecule with substituents at 1 and 2 positions on an aromatic compound
ORTHO
o describe a molecule with substituents are at the 1 and 3 positions on an aromatic compound
META
a molecule with substituents at the 1 and 4 positions on an aromatic compound
PARA
BENZENE-1
,
2-DIOL
CATHECHOL
BENZENE-1
,
3-DIOL
RESORCINOL
BENZENE-1,4-DIOL
HYDROQUINONE
TWO METHYL GROUP
XYLENE
ONE METHYL AND ALCOHOL
CRESOL
ALCOHOL
PHENOL
Positions are indicated with number
Benzene
with Three or
More Substituents
The ring is numbered in a way as to obtain the
lowest
possible numbers for
carbon
atoms with substituent
Benzene
with
Three
or More Substituents
If there is a choice of numbering systems, the group that comes first alphabetically is given the lowest number.
Benzene
with Three or
More Substituents