The volume of a fixed amount of gas is inversely proportional to its pressure, when the temperature is constant.
Boyle's Law
If pressure increases, volume decreases
If pressure decreases, volume increases
Charles Law (volume-temperature relationship)
At a constant pressure, the volume of a gas is directly proportional to the absolute temperature.
Charles Law
If temperature increases, volume increases
If temperature decreases, volume decreases
Gay-Lussac's Law (Pressure-Temperature)
The pressure of a gas is directly proportional to its absolute temperature, when the volume is fixed.
Gay-Lussac's Law
If temperature increases, pressure increases
If temperature decreases, pressure decreases
Ideal Gas Law
If the gas is at a low pressure and a high temperature the density of the gas is going to be very low, so it can be considered that there are no interactions between the gas molecules and the volume of the molecules is zero.
Combined Gas Law
This law establishes the relationship between the pressure, volume, and absolute temperature of a fixed amount of gas
Law of Partials Pressures
The total pressure of a mixture of gases is the sum of the partial pressure exerted by each of the gases that make up the mixture.
Thermodynamics:
This is the part of physics that studies the heat and work exchanges that accompany physicochemical processes.
Chemical Thermodynamics
The relationship between chemical reactions and the energy changes that involve the heat associated with said chemical changes.
Chemical Kinetics:
Studies the speed at which a chemical process occurs and the factors that affect it.
Energy
The ability to do work or transfer heat
Work (W)
s the energy used to achieve the displacement of a body a certain distance (d) against a certain force (F)
Heat (Q):
Is defined as the form of energy that is transferred due to a temperature difference
Exothermic Reaction
Release of energy
Endothermic Reaction
Absorption of energy
Thermodynamic System
Is the portion of the universe that is taken for study, and the environment is the rest of the universe that is outside the system and that can act on it or not.
System + Natural environment = Universe
Thermodynamics system classification
Open system
Closed system
Isolated system
Open Systems:
They can exchange energy and matter with their environment
Closed systems:
They can exchange energy, but their mass remains constant, they cannot leave or enter.
Isolated Systems:
Cannot exchange energy or matter with their environment
State of aggregation of the components:
Homogeneous
Heterogeneous
Homogeneous
It's made up of a single phase
Heterogeneous
It consists of more than one phase.
Thermodynamic Variables
Extensive
Intensive
Extensive Variables
The extensive variables depend on the mass of the system.
Intensive Variables
Intensive variables are independent of the mass of the system
Entropy (s)
magnitude that indicates the energy that cannot do useful work in a thermodynamic process.
Entalphy (H)
Meassure of the termal energy of a chemical system
Free Energy (G)
It is a measure of the amount of energy available to carry out a job in the system.
Internal Energy
The total energy (kinetic and potential) that a system has due to the particles that make it up.
Heat Capacity
The amount of heat absorbed or given, required to change the temperature of said substance by 1 C.
Heat of Reaction
It is the heat absorbed or released in a process or chemical reaction.