The study of the relations between heat, work, temperature, and energy
First law of thermodynamics
The change in internal energy of a system is equal to the heat added to the system minus the work done by the system
Joule's mechanical equivalent of heat
The amount of work required to produce 1 calorie of heat
Calorie
The energy that would be required to raise one gram of water by one degree Celsius
Calorie (capital C)
The unit used on food labels
Calorific value
The amount of heat energy present in food or fuel and which is determined by the complete combustion of specified quantity at constant pressure and in normal conditions
Heat of combustion
The amount of heat liberated when a given amount of the substance undergoes combustion
Heating value
The amount of heat released during the combustion of a specified amount of a substance
Mercury thermometer
Uses mercury as the thermometric liquid, mercury has a higher freezing point compared to alcohol
Alcohol thermometer
Uses alcohol as the thermometric liquid
Thermocouple
A sensor used to measure temperature, consisting of two wire legs made from different metals welded together at one end
RTD (Resistance Temperature Detector)
Uses the property that the resistance of a conductor changes with temperature
Thermistor
A type of resistor whose resistance varies significantly with temperature
Latent heat
The heat or energy that is absorbed or released during a phase change of a substance
Expansion
An increase in size of an object when heat is applied
Bimetallic strip
Used to convert a temperature change into mechanical displacement, consisting of two strips of different metals which expand at different rates when heated
Heat
A measure of the total energy of molecular motion
Latent heat of fusion (Lf)
The heat supplied to cause a substance to change from the solid state to the liquid state
Latent heat of vaporization (Lv)
The heat required to change a substance from the liquid state to the gaseous state
Conduction
Heat transfer from one molecule to nearby molecules
Convection
Heat transfer by movement of fluids (gases or liquids)
Radiation
Heat transfer by electromagnetic radiation
Greenhouse effect
Radiant heat energy entering a closed building or vehicle is reflected, causing the interior to become much warmer than the outside
Kinetic-molecular theory of gases
Assumes ideal gas molecules are constantly moving, have negligible volume and intermolecular forces, undergo perfectly elastic collisions, and have average kinetic energy proportional to absolute temperature
Adiabatic process
No heat transfer, ΔU = -W
Isothermal process
Constant temperature, ΔU = 0, Q = W
Isobaric process
Constant pressure, ΔU, W, and Q are generally non-zero, W = P·ΔV
Isochoric process
Constant volume, W = 0, ΔU = Q
Thermodynamic cycle
A closed system that undergoes various changes in temperature, pressure, and volume, with the final and initial states being equal
Power cycles
Cycles that convert heat input into mechanical work output
Heat pump cycles
Cycles that transfer heat from low to high temperatures using mechanical work as input
Carnot cycle
An ideal reversible closed thermodynamic cycle with isothermal expansion, adiabatic expansion, isothermal compression, and adiabatic compression
Diesel cycle
An ideal-engine cycle with adiabatic compression, constant-pressure heating, adiabatic expansion, and constant-volume cooling
Otto cycle
An ideal thermodynamic combustion cycle with compression at constant entropy, constant-volume heat transfer, expansion at constant entropy, and constant-volume heat transfer
Brayton cycle
The thermodynamic cycle used in jet engines, involving an isobaric process in the combustor and isentropic processes
Aerospace engineers rely on thermodynamics to understand and optimize the performance of propulsion systems, as the efficiency depends on effective conversion of fuel potential energy into kinetic energy