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ANACHEM LAB
EXP 9
Nickel
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NICKEL (Ni2+)
is a
hard
,
silvery-white metal
, it is
ductile
,
malleable
and
very strong.
It
melts
at
1455°C
, and is
slightly magnetic.
HCl (both dilute and concentrated)
and
dilute H2SO4
dissolve
nickel with the formation of
hydrogen gas.
concentrated
,
hot H2SO4 dissolves
nickel with the formation of
sulfur dioxide (SO2) gas.
Cold
,
dilute
and
concentrated HNO3 dissolve
nickel readily with the evolution of
nitrogen dioxide (NO2) gas.
The
stable nickel (II) salts
are derived from
nickel (II) oxide
,
NiO
, which is a
green
substance.
The
dissolved nickel (II) salts
are
green
, owing to the color of the
hexaquonickelate
(II) ion complex [Ni(H2O)6]2
+; or simply the
Nickel (II) ion.
A
brownish-black
nickel
(III)
oxide Ni2O3
also exists, but this
dissolves
in
acids
forming
nickel (II) ions.
With
dilute
HCl
this reaction yields
chlorine
gas.
While nickel forms two series of compounds, only those in which it has a
valence of two (+2) are important.
Compounds of nickel generally have a
bright green
color which they impart to their solutions.