explain why heating a system will change the energy stored within the system and raise its temperature or produce changes of state
heating a system involves transferring energy to the particles of molecules within the system
this increases the kinetic energy of the particles which means the internal energy of the system increases, which increases the temperature
this can also produce a change of state if the energy supplied is used to overcome the forces holding the molecules together as opposed to increasing the kinetic energy
this does not increase the temp. because no energy goes towards increasing the kinetic energy of the system
describe an experiment to show constant temperature during a change of state
fill a beaker with boiling water
put ice in the beaker and record the temperature of the ice every 10s as it melts
the results should be a straight line on a temperature/time graph as the energy in the ice goes towards breaking the bonds in the ice rather than increasing its kinetic energy
5.14) describe an experiment to investigate the specific heat capacity of materials including water and some solids
measure the mass of an insulating container, fill it with 200ml water and then measure the mass again (the difference between these numbers is the mass of the water)
measure the temperature of water and turn on power which is connected to the water by a immersion heater and connect it to voltmeter and ammeter
wait 1 minute and then measure the water temperature and take voltmeter and ammeter measurements
calculate energy supplied using equation: energy supplied = voltage x current x time
substitute the answer as Q in the equation Q=mcΔT to find specific heat capacity
5.7) which changes occur to melt a solid into a liquid
solids can't move so they have no net kinetic energy
as they are heated, the particles vibrate so kinetic energy is gained
kinetic energy increases → particles vibrate more → frequency of collisions increases → particles get further away from eachother and become liquid because they break free of their previous bonds
explain the relationship between pressure and volume at constant temperature (boyle's law)
if temperature is constant, average particle speed is constant
as
volume decreases in a container, particle collision frequency per second increases
this is because the same amount of particles are moving around in a smaller volume so they are more likely to hit the sides
more collisions exerted per second on the sides means that the particles exert a greater force on the wall over a given time, so the average force exerted on the walls increases
this means that the total pressure exerted by the particles increases:
pressure is force / area, and the force here increases while the area stays the same
this means that the relationship between pressure and volume is inversely proportional: as volume decreases, pressure increases and vice versa
equation for the relationship between the pressure and Kelvin temperature of a fixed mass of gas at constant volume
P₁/T₁ = P₂/T₂
temperature must always be in kelvin
P₁ = (P₂*T₁)/T₂
P₂ = (P₁*T₂)/T₁
T₁ = (T₂*P₁)/P₂
P₂ = (P₁*T₂)/T₁
if youre arranging for P₁, you need to divide by the opposite letter and the opposite number so you need to divide by T₂. then put the other values (P₂*T₁) over the T₂
equation for the relationship between the pressure and volume of a fixed mass of gas at constant temperature
P₁V₁ = P₂V₂
if youre arranging for P₁, put the value with the same number but the opposite letter underneath the dividing sign (so you put T₁ under the division sign), and then multiply the other numbers over the division sign