Romans: Developed lime putty and volcanic ash mixture for early cement.
Manufacturing Process of Lime
1. Calcination of limestone
2. Carbonates decompose into carbon dioxide and quicklime (calcium oxide, CaO)
Preparation of Lime
Quicklime must be mixed with water in the slaking or hydration process
Hydration of Lime
Quicklime + Water → Calcium Hydroxide (slaked lime or hydrated lime, Ca(OH)2)
Applications of Hydrated Lime
Ingredient in hard-finish coat for two-and three-coat Portland cement plasters
Mixing with cement mortar or concrete for increased workability, decreased permeability to water, reduced cracking due to shrinkage
Hydraulic Lime
Lime type that sets underwater, used for slow underwater setting requirements
Plasticity Enhancement
Addition of hydrated lime renders gypsum plaster more plastic
Cohesiveness Improvement
Fiber or hair is sometimes added for greater cohesiveness
Fiber Types
Hemp, sisal, or jute fibers
Hair Types
Cleaned goat or cattle hair
Roman Development of Cement
Romans mixed slaked lime with pozzolana (volcanic ash), creating a hydraulic cement that hardened underwater
Englishman Smeaton rediscovered hydraulic cement
1756
English bricklayer and mason Aspdin invented and patented Portland cement
1824
Portland Cement
Today, "cement" typically refers to Portland cement, the principal type in use
Manufacturing Process of Portland Cement
Obtained by finely pulverizing clinker produced from calcining a mixture of argillaceous (silica, alumina) and calcareous (lime) materials with iron oxide and other ingredients
Types of Portland Cement
Slow-setting cement
Quick-setting high early strength cement
Sulfate-resisting cement for applications with alkaline water and soils
White cement (or stainless cement) free of iron impurities
STORAGE OF CEMENT
Protection from Dampness
Cement should be shielded from dampness at the building site
Storage Conditions
Stored in a shed with a wood floor raised about 300mm (12") from the ground
Inspection for Moisture Damage
Cement should feel soft and silky to the touch, presence of lumps that do not readily break indicates moisture absorption, which can be damaging
Prompt Usage
Cement should be used as soon as possible after delivery to prevent moisture damage
Pile Height Limitation
Piles of cement should be limited to twelve sacks in height to prevent pressure-induced hardening of lower layers
Warehouse Set Prevention
Avoid storing cement in high piles for extended periods to prevent hardening of lower layers due to pressure
Definition of Concrete
Proportioned mixture of cement, aggregate, and water
Properties of Concrete
Plastic mass can be cast, molded, or formed into predetermined size or shape
Upon hydration, it becomes stone-like in strength, hardness, and durability
Setting
Hardening of concrete
Variants of Concrete
Mortar, Stucco, Or Cement Plaster
Concrete
Reinforced Concrete
Plain or Mass Concrete
Qualities of Good Concrete
Strength
Durability
Uniform Quality
Thoroughly Sound
Achieved Through
Careful Material Selection
Correct Proportioning
Thorough Mixing
Careful Transporting and Placing
Proper Curing or Protection
MATERIALS OF CONCRETE
Usual Tests for Cement
Soundness (constancy of volume)
Time of setting
Fineness
Tensile strength
Cement Quantity per Bag
Approximately 1 cu. ft., weighs 94 lbs
Recommended Cement for Reinforced-Concrete Construction
High-grade Type 1 Portland cement (ASTM C-150)
Fine Aggregates
Smaller than 6mm / ¼" in size, consist of sand, stone screenings, or similar inert materials, specifications: 80-95% pass No. 4 wire cloth sieve; 10-30% pass No. 50 sieve
Coarse Aggregates
Larger than ¼" in size, consist of crushed stones, gravel, or similar inert materials, should be well graded and not exceed 25mm / 1" in size for reinforced beams, floor slabs, etc.
Special Aggregates
Cinders, blast furnace slag, etc., can produce lightweight or thermal insulating concrete