Line the inside of the chest wall (the ribs) and also the outside of the lungs
Reduce friction during breathing as the lungs fill with air and deflate
The space between the pleural membranes in the pleural cavity contains a small amount of pleural fluid which helps to further reduce friction during breathing
This is where gas exchange takes place between the atmosphere and the blood
Oxygen diffuses into the blood from the alveoli and carbon dioxide goes the other way, diffusing from the blood into the alveoli, where it is breathed out