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BSCE-1
CHEM
Polymers
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Polymer
A long-chain molecule made up of many
repeating
units, called
monomers
Classifications of Polymers
Source of
Availability
Structure of the
Monomer
Chain
Number of
Monomers
Mechanical
and
Thermal
Behavior
Classification
of Polymers based on the Source of Availability
Natural
Polymers
Semi-Synthetic
Polymers
Synthetic
Polymers
Classification
of Polymers based on the Structure of the Monomer Chain
Linear
Polymers
Branched-Chain
Polymers
Cross-Linked
Polymers
Classification
of Polymers Based on Monomers
Homomer
Heteropolymer
/
Copolymer
Classification
of Polymers Based on Mechanical and Thermal Behavior
Thermoplastics
Thermosets
Elastomers
Thermoplastics
Polypropylene
Polyvinyl chloride
Polyester
Thermoplastic
Any plastic polymer material that becomes pliable or
moldable
at a certain elevated temperature and
solidifies
upon cooling
Thermosets
epoxy
silicone
Thermoset
A polymer that is obtained by irreversibly hardening ("curing") a soft solid or viscous liquid
prepolymer
(resin)
Elastomers
polyisoprene
polychloroprene
Types
of Polymerization
Addition
Condensation
Condensation
Polymerization
Step-growth
polymerization
A relatively small molecule (such as water, ethanol, methanol, etc.) is formed as a result of the
polymerization
reaction
This mechanism may often involve different
monomers
as starting or
precursor
molecules