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AS chemistry group 2
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Group II metals
Lose two electrons to form
2+
ions when they react in order to achieve a
full outer shell
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Atomic radius of group II metals
Increases
down the group due to
additional
electron shells
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Reactivity of group II metals
Increases
down
the group due to increased electron shielding making the
outer
electrons easier to lose
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First
ionisation
energy of group II metals
Decreases
down the group due to a greater atomic radius and increased amounts of
shielding
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Melting point
of group
II
elements
Decreases
down the group as the larger ions within the metallic structure have
weaker
attractive forces acting over a greater distance
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Reaction of group II metals with water
1. Metal is
oxidised
from OS
0
to OS +2
2. Produces a
metal hydroxide
and hydrogen
3. Metal
hydroxide
forms an
alkaline
solution
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Reaction of magnesium with water
Magnesium reacts
slowly
with liquid water
Reaction is
faster
with steam as it provides extra
energy
Magnesium burns with a bright
white
flame to form hydrogen and magnesium
oxide
(a white powder)
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Solubility of group II hydroxides
Increases
down the group, with magnesium hydroxide being the
least
soluble and barium hydroxide being the most soluble
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Uses of magnesium hydroxide
Used as an
antacid
in medicine to
neutralise
acids
Used in
agriculture
to
neutralise acidic
soils
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Solubility of group II sulfates
Decreases
down the group, with
magnesium
sulfate being the most soluble and barium sulfate being the least soluble
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Use of
barium sulfate
Used in medicine as
barium meals
, a form of
medical tracer
that allows internal tissues and organs to be imaged
Insoluble so cannot be absorbed into the
bloodstream
, making it
safe
to use
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Use of barium chloride
Used as a test for
sulfate
ions, reacting to form a
white
precipitate of barium sulfate
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Magnesium used in the
extraction
of
titanium
Displacement
reaction with
titanium chloride
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Calcium
oxide
used in flue gas removal
Reacts with
sulfur dioxide
to form calcium sulfite and water, removing sulfur dioxide from
factory pollutants
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