What is the structure of starch?
Starch is a polysaccharide, made of two types of polymers: amylose and amylopectin.
Amylose is made from glucose molecules linked by 1-4 glycosidic bonds, they are long unbranched chains held together by hydrogen bonds - this makes them compact and easy to store.
Amylopectin is made from glucose chains linked together by 1-6 glycosidic bonds, in a branched structure. This increases surface area for enzymes to hydrolyse glycosidic bonds allowing glucose to be released quickly.