Group 3

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  • Period 3 Oxides
    • Reactions with oxygen
    • Reactions with chlorine
    • Reaction of sodium with water
    • Reaction of magnesium with water
    • Oxidation number of Period 3 oxides
    • Reaction of Period 3 oxides with water
  • Reaction of sodium with cold water
    • 2Na(s) + 2H2O(l) → 2NaOH(aq) + H2(g)
    • Sodium melts into a ball and moves across the water surface until it disappears
    • Hydrogen gas is given off
    • The solution formed is strongly alkaline (pH 14) due to the sodium hydroxide which is formed
  • Reaction of magnesium with cold water
    • Mg(s) + 2H2O(l) → Mg(OH)2(aq) + H2(g)
    • The solution formed is weakly alkaline (pH 11) as the formed magnesium hydroxide is only slightly soluble
    • When magnesium is heated, it reacts vigorously with steam (water) to make magnesium oxide and hydrogen gas: Mg(s) + H2O(g) → MgO(s) + H2(g)
  • Electronegativity of oxygen
    Oxygen is more electronegative than any of the Period 3 elements
  • Oxidation states of Period 3 elements in their oxides
    The Period 3 elements have positive oxidation states in their oxides and the oxygen has a negative oxidation state of -2
  • Formulae of the oxides of the Period 3 elements & their oxidation states
    • Oxide formula
    • Oxidation state of Period 3 element
  • Since aluminium oxide does not react or dissolve in water, the oxide layer protects the aluminium metal from corrosion
  • Period 3 oxides react with or are soluble in water
  • Reaction of Period 3 oxides with water