A diagram showing alternative routes between reactants and products which allows the indirect determination of an enthalpy change from other known enthalpy changes using Hess's law
Hess' law states if a reaction can take place by more than one route and the initial and final conditions are the same, the total enthalpy change is the same for each route
when drawing enthalpy change of formation cycle, arrows go up
When drawing enthalpy change of combustion cycle, arrows go down
enthalpy changes of formation = ΔfH of products - ΔfH of reactants
enthalpy changes of combustion = ΔcH of reactants - ΔcH of products