Oxidation of alcohol

Cards (9)

  • Define primary alcohol
    The carbon that is attached to the OH is attached to none or one other carbon atom
  • Define secondary alcohol
    The carbon attached to the OH is attached to two other carbon atoms
  • Define tertiary alcohol
    The carbon attached to the OH is attached to three other carbon atoms
  • How is an aldehyde formed?
    Primary alcohol is mixed with an oxidising agent
    2 H atoms are removed
  • What is a suitable oxidising agent?
    Acidified potassium dichromate
    K2Cr2O7
  • How is a ketone produced?
    A secondary alcohol is mixed with an oxidising agent, 2 H atoms are removed
  • How is a carboxylic acid produced?
    An aldehyde is mixed with an oxidising agent
    An oxygen atom is added
  • What apparatus is used for aldehydes, ketones and carboxylic acids?
    Distillation apparatus - aldehyde and ketones
    Reflux apparatus - carboxylic acids
  • Name and explain the two ways to distinguish between aldehydes and ketones
    Tollen's Reagent
    • Aldehydes are reducing agents
    • Ag+ ions are reduced to metallic silver
    • There is a silver mirror in a positive test
    Fehling's Solution
    • Aldehydes are reducing agents
    • Cu2+ is an oxidising agent, they react
    • There is a brick red precipitate in a positive test