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Organic
Alcohols
Oxidation of alcohol
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Created by
Niamh Mumby
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Cards (9)
Define primary alcohol
The
carbon
that is attached to the
OH
is attached to
none
or
one
other
carbon
atom
Define secondary alcohol
The
carbon
attached to the
OH
is attached to
two
other
carbon
atoms
Define tertiary alcohol
The
carbon
attached to the
OH
is attached to
three
other
carbon
atoms
How is an aldehyde formed?
Primary
alcohol is mixed with an
oxidising
agent
2
H atoms are removed
What is a suitable oxidising agent?
Acidified potassium dichromate
K2Cr2O7
How is a ketone produced?
A secondary alcohol is mixed with an
oxidising
agent,
2
H atoms are removed
How is a carboxylic acid produced?
An
aldehyde
is mixed with an oxidising agent
An
oxygen
atom is added
What apparatus is used for aldehydes, ketones and carboxylic acids?
Distillation
apparatus - aldehyde and ketones
Reflux
apparatus - carboxylic acids
Name and explain the two ways to distinguish between aldehydes and ketones
Tollen's Reagent
Aldehydes are reducing agents
Ag
+ ions are reduced to metallic
silver
There is a
silver mirror
in a positive test
Fehling's Solution
Aldehydes are
reducing
agents
Cu2+ is an
oxidising
agent, they react
There is a
brick red
precipitate in a positive test