energy changes

Cards (52)

  • What is the conservation of energy principle?
    Energy is conserved in chemical reactions. The amount of energy in the universe at the end of a chemical reaction is the same as before the reaction takes place.
  • What is an exothermic reaction? Give examples
    A reaction where energy is transferred to the surroundings so that the surroundings temperature increases - combustion, oxidation reactions and neutralisation (acid + alkali) reactions. Negative sign of energy change.
  • What is an endothermic reaction? Give examples
    A reaction where energy is taken in from the surroundings so the surroundings temperature decreases - thermal decomposition, reaction of citric acid and sodium hydrogencarbonate. Negative sign of energy change.
  • What is activation energy.
    Minimum amount of energy that particles need to react
  • What is a reaction profile?
    Reaction profile is a graph which shows the relative energies of reactants and product, as well as activation energy of the reaction.
  • What occurs in a chemical reaction in terms of bond energies?
    Energy is supplied to break bonds and energy is released when bonds are made
  • Describe rechargeable and non-rechargeable cells
    Rechargeable - chemical reactions are reversed when an external current is supplied
    Non-rechargeable - reactants are used up, cannot be recharged
  • What is the principle of energy conservation in chemical reactions?
    The total amount of energy in the universe remains the same before and after a reaction.
  • What happens to energy during an exothermic reaction?
    Energy is transferred to the surroundings, causing the temperature of the surroundings to increase.
  • What are some examples of exothermic reactions?
    Combustion reactions, many oxidation reactions, and most neutralisation reactions.
  • What are everyday uses of exothermic reactions?
    Self-heating cans and hand warmers.
  • What occurs during an endothermic reaction?
    Energy is taken in from the surroundings, causing the temperature of the surroundings to decrease.
  • What are some examples of endothermic reactions?
    Thermal decomposition reactions and the reaction of citric acid with sodium hydrogencarbonate.
  • What is a common everyday use of endothermic reactions?
    Instant ice packs used to treat sports injuries.
  • What does an energy level diagram show in a chemical reaction?
    • Energy in the reactants and products
    • Difference in energy between reactants and products
    • Indicates whether the reaction is exothermic or endothermic
  • How does the energy level change in an exothermic reaction?
    The energy level decreases because energy is given out to the surroundings.
  • How does the energy level change in an endothermic reaction?
    The energy level increases because energy is taken in from the surroundings.
  • What is a reaction profile and what does it include?
    • Shows how energy changes during a reaction
    • Includes activation energy
    • Indicates the energy of reactants and products
  • What is activation energy?
    It is the minimum energy needed by particles when they collide for a reaction to occur.
  • How is activation energy represented in a reaction profile?
    As a 'hump' in the line that starts at the energy of the reactants.
  • What determines whether a reaction is exothermic or endothermic?
    The difference between the energy needed to break bonds and the energy released when new bonds are made.
  • When is a reaction considered exothermic?
    When more heat energy is released in making bonds in the products than is taken in when breaking bonds in the reactants.
  • When is a reaction considered endothermic?
    When less heat energy is released in making bonds in the products than is taken in when breaking bonds in the reactants.
  • What do chemical cells use to transfer energy?
    Chemical reactions
  • What factors affect the voltage of a chemical cell?
    The materials of the electrodes and the substance used as the electrolyte
  • How can a simple cell be made?
    By connecting two different metals in contact with an electrolyte
  • What happens when multiple cells are connected in series?
    The voltage increases compared to a single cell
  • What occurs in non-rechargeable cells when one of the reactants is used up?
    The battery 'goes flat'
  • How do rechargeable cells and batteries work?
    The chemical reactions can be reversed when an external circuit is supplied
  • What do fuel cells require to produce voltage continuously?
    A constant supply of a suitable fuel and oxygen
  • How is the fuel oxidised in fuel cells?
    Electrochemically, rather than being burned
  • What type of energy is released by fuel cells?
    Electrical energy
  • What are the pros and cons of alkaline cells, rechargeable cells, and hydrogen fuel cells?
    Alkaline Cell:
    • Pros: Cheaper to manufacture
    • Cons: May end up in landfill sites once fully discharged

    Rechargeable Cell:
    • Pros: Can be recharged many times, reducing resource use
    • Cons: Costs more to manufacture

    Hydrogen Fuel Cell:
    • Pros: Small size; water is the only chemical product
    • Cons: Very expensive to manufacture; needs a constant supply of hydrogen fuel
  • In what applications are fuel cells commonly used?
    In spacecraft and vehicles
  • What is the process of electrolysis?
    Decomposition of ionic compounds using electricity.
  • What is an electrolyte?
    A liquid that conducts electricity.
  • What does it mean to discharge in the context of electrolysis?
    To gain or lose electrons to become electrically neutral.
  • What is the role of the anode in electrolysis?
    It is the electrode where oxidation takes place and is the positive electrode.
  • What occurs at the cathode during electrolysis?
    Reduction takes place, which is the gain of electrons, and it is the negative electrode.
  • What are the key terms related to electrolysis and their definitions?

    • Electrolysis: Decomposition of ionic compounds using electricity.
    • Electrolyte: A liquid that conducts electricity.
    • Discharge: Gain or lose electrons to become electrically neutral.
    • Anode: Electrode where oxidation takes place (positive electrode).
    • Cathode: Electrode where reduction takes place (negative electrode).