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Chemistry
Organic I
alcohol
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Created by
Melissa Kana
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Cards (21)
What functional group do alcohols contain?
OH group
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What is the general formula for
alcohols
?
C
n
_n
n
H
2
n
+
1
_{2n+1}
2
n
+
1
OH
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What are the two main methods for producing alcohols?
Hydration of alkenes
Fermentation of sugars
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How are alcohols produced from alkenes?
Through hydration in the presence of an acid catalyst
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What acid is commonly used as a catalyst in the hydration method?
Phosphoric acid
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What conditions are required for the hydration method of alcohol production?
Aqueous conditions at 300°C and high pressures
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Why is the hydration method favored as an industrial process?
It has a very high percentage yield with ethanol as the only product
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What is the process of fermentation in alcohol production?
Enzymes break down starch into sugars which are then fermented
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Why is fermentation considered cheaper than hydration?
It can be carried out at a lower temperature
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What is a disadvantage of the
fermentation
process?
It is a much slower process with a lower
percentage
yield
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What is ethanol commonly produced from fermentation known as?
A biofuel
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Why is ethanol considered carbon neutral?
The carbon emitted when burned equals the carbon absorbed by crops during growth
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What types of alcohols can be oxidized?
Primary (1°) and secondary (2°) alcohols
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What happens to 1° alcohols when heated with acidified potassium dichromate?
They can be oxidized to produce aldehydes
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What occurs when 1° alcohols are heated further under reflux conditions?
They oxidize further to produce carboxylic acids
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What do 2° alcohols produce when oxidized with acidified potassium dichromate?
Ketones
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What is the role of potassium dichromate in the oxidation of alcohols?
It acts as the oxidizing agent
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What color change indicates the oxidation of alcohols using potassium dichromate?
From orange to green
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What is the
dehydration
process of alcohols to form
alkenes
?
A molecule of water is removed
Excess hot
sulfuric acid
is added
Aluminium oxide
is used as a catalyst
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How do H
+
^+
+
ions act in the dehydration reaction of alcohols?
They are reformed in the reaction, acting as a catalyst
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How does fermentation contribute to the production of
addition polymers
?
Fermentation
produces
primary alcohol
Primary alcohol is dehydrated to produce an
alkene
Alkenes are used in the production of addition polymers
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