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Module 5
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Cards (117)
What is the Arrhenius Equation?
k =
Ae
−
E
a
/
R
T
-Ea/RT
−
E
a
/
RT
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What does the rate constant (k) represent in the Arrhenius Equation?
It relates
reaction rate
to
temperature
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What is a Clock Reaction?
A reaction measuring time for a
visible change
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How is Colorimetry used in chemistry?
To measure light
absorbed
by a solution
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What does a Concentration-time Graph plot on its axes?
Concentration on
y-axis
and time on
x-axis
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What does the gradient of a Concentration-time Graph represent?
The
rate of reaction
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What is Continuous Monitoring in a rate experiment?
Taking
continuous
measurements
as
the
reaction
progresses
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What is a First Order Reactant?
A reactant whose rate doubles when
concentration
doubles
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How is the gradient calculated?
Change in y
÷
change in x
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What is Half-life (t
1
/
2
_{1/2}
1/2
)?
The time for
concentration
to
halve
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What is the Initial Rate of a reaction?
The rate at time
t=0
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What does Order refer to in a reaction?
A number relating rate to
reactant
concentrations
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How is Overall Order determined?
Sum of the orders with respect to each
reactant
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What is the Rate Constant (k)?
A
constant
relating
rate
to reactant
concentrations
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How can k be determined for a first order reaction?
Using k =
ln 2
/t
1
/
2
_{1/2}
1/2
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What does a Rate-concentration Graph plot on its axes?
Concentration
on x-axis and
rate
on y-axis
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What is the Rate-determining Step?
The
slowest
step of a reaction
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What does the Rate equation relate?
Rate to
concentrations
of
reactants
and
k
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What is the Rate of Reaction?
A measure of how quickly
reactants
are used
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What is a Reaction Mechanism?
A
step-by-step
sequence of individual reactions
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What is a Second Order Reactant?
A reactant whose rate
quadruples
when concentration
doubles
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What is a Zero Order Reactant?
A reactant that has no impact on the
rate
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What is a Catalyst?
A substance that speeds up a
reaction
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How is Concentration defined?
Amount of
substance
per
unit volume
of solution
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What characterizes an Endothermic reaction?
It takes in energy from
surroundings
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What is Equilibrium in a chemical reaction?
Forward and reverse reactions occur at the same
rate
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What is the Equilibrium Constant (K)?
A value relating
products
and
reactants
at equilibrium
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How does temperature affect the Equilibrium Constant (K)?
K
is affected by
temperature
changes
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What is Heterogeneous Equilibrium?
Equilibrium involving substances in different
states
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What is Homogeneous Equilibrium?
Equilibrium involving
substances
in the same state
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What is K
c
_{c}
c
?
Equilibrium constant based on
concentrations
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How is K
c
_{c}
c
calculated?
Products' concentrations raised to
stoichiometric
coefficients
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What is K
p
_{p}
p
?
Equilibrium constant based on
partial pressures
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How is K
p
_{p}
p
calculated?
Products' partial pressures raised to
stoichiometric
coefficients
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What does Partial Pressure (P
A
_{A}
A
) represent?
Pressure exerted by one gas in a mixture
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What is the Acid Dissociation Constant (K
a
_{a}
a
)?
Extent of acid dissociation
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How is pK
a
_{a}
a
calculated?
pK
a
_{a}
a
= -
log
(K
a
_{a}
a
)
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What is a Bronsted-Lowry Acid?
A
proton
donor
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What is a Bronsted-Lowry Base?
A
proton
acceptor
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What is a Buffer Solution?
A system that minimizes
pH
change
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