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Module 5
5.1.1
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Cards (33)
What is the Arrhenius Equation?
k = Ae
−
E
a
/
R
T
-Ea/RT
−
E
a
/
RT
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What is a Clock Reaction?
A reaction measuring time for a
visible change
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What does the rate constant (k) represent in the Arrhenius Equation?
It relates
reaction rate
to
temperature
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What does Colorimetry measure?
The amount of light
absorbed
by a solution
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How is a calibration curve used in Colorimetry?
To relate
absorbance
to
concentration
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What does a Concentration-time Graph plot on the axes?
Concentration on
y-axis
and time on
x-axis
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What does the gradient of a Concentration-time Graph represent?
The
rate of reaction
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What is Continuous Monitoring in a rate experiment?
Taking
continuous
measurements
as the
reaction
progresses
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What happens to the rate when the concentration of a first order reactant is doubled?
The rate also
doubles
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What is the formula for Gradient?
Change in y
÷
change in x
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What is Half-life (t1/2)?
The time for concentration to halve
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What is Initial Rate?
The rate at
t=0
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What does Order refer to in a reaction?
A number relating rate to
reactant
concentrations
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What is Overall Order?
The sum of the orders of each
reactant
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What is Rate Constant (k)?
A
constant
relating
rate
to reactant
concentrations
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How can k be determined for a first order reaction?
Using k = ln (2/t)x1/2
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What does a Rate-concentration Graph plot on the axes?
Concentration
on x-axis and
rate
on y-axis
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What is the Rate-determining Step?
The
slowest
step of a reaction
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What does the Rate equation relate?
Rate to
reactant
concentrations
and
rate constant
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What is the Rate of Reaction?
A measure of how quickly
reactants
are used
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What is a Reaction Mechanism?
A
step-by-step
sequence of reactions
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What happens when the concentration of a second order reactant is doubled?
The
rate
quadruples
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What happens when the concentration of a zero order reactant is doubled?
No impact on the
rate
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What is a Catalyst?
A substance that speeds up a
reaction
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What does Concentration measure?
Amount of
substance
per
unit volume
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What is an Endothermic reaction?
A reaction that
takes
in
energy
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What is Equilibrium in a reaction?
Forward
and
reverse
reactions occur at the same
rate
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What is the Equilibrium Constant (K)?
Relates
products
and
reactants
at equilibrium
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How does temperature affect the Equilibrium Constant (K)?
K is
affected
by temperature changes
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What is Heterogeneous Equilibrium?
Involves substances in different
states
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What is Homogeneous Equilibrium?
Involves
substances
all in the same state
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What is Kc?
The equilibrium constant for concentrations
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What does Kc exclude in heterogeneous expressions?
Liquids and solids
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