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AQA: a-level chemistry
inorganic
1. periodicity
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Created by
Amal Azab
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Cards (32)
How are elements arranged in the periodic table?
By
proton number
, not
mass number
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What do groups in the periodic table represent?
Columns
of elements
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How many electrons do group one elements have in their outer shell?
One
electron
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What happens to the reactivity of group one elements with water?
They react
violently
, increasing down the group
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What do elements in the same period have in common?
They have the same number of
electron shells
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What are periods in the periodic table?
Rows
of
elements
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What are the four blocks of elements in the periodic table?
S
,
P
,
D
, and
F
blocks
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What happens to atomic radius as you go across period 3?
It
decreases
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What happens to atomic radius as you go down a group?
It increases
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Why does atomic radius decrease across a period?
Increased
nuclear charge
pulls electrons closer
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What is the effect of shielding on atomic radius?
It protects inner electrons from the
nucleus
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Why does atomic radius increase down a group?
Extra
electron shells
are added
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What is the trend in melting points for metals in period 3?
They generally
increase
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Why does magnesium have a higher melting point than sodium?
Magnesium has a higher
positive charge
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What type of structure does silicon have?
Giant covalent
structure
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What determines the melting point of phosphorus?
Van der Waals forces
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Why does sulfur have a higher melting point than phosphorus?
It has larger
Van der Waals forces
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What is the melting point of chlorine compared to sulfur?
Chlorine has a
lower
melting point
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What is ionization energy?
Energy required to remove an
electron
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What is the trend in ionization energy across a period?
It
generally
increases
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What effect does shielding have on ionization energy?
More shielding means less energy required
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What happens to ionization energy as you go down a group?
It
decreases
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Why does ionization energy decrease down a group?
Outer electrons
are further from the
nucleus
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What is successive ionization?
Removing more than one
electron
from an atom
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What causes the jumps in successive ionization energy?
Removing electrons from
shells
closer to the
nucleus
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What is the significance of the subshell theory?
It explains
ionization energy
trends across
periods
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Why does aluminum have lower ionization energy than magnesium?
Its
outer electron
is in a higher energy
subshell
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What causes the decrease in ionization energy for sulfur?
Electron repulsion
in the same
subshell
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What are the key concepts in periodicity?
Shielding
Nuclear charge
Atomic radius
Trends
in
ionization energy
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What are the trends in melting points across period 3?
Sodium, magnesium, aluminum: increase
Silicon: much higher due to
covalent bonds
Phosphorus: lower due to
Van der Waals forces
Sulfur: higher than phosphorus due to larger molecules
Chlorine: lower due to smaller molecules
Argon: lowest,
monoatomic
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What factors affect ionization energy?
Atomic size
Nuclear charge
Shielding effect
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What are the exceptions in ionization energy trends?
Aluminum
: lower than magnesium due to
subshell
Sulfur: lower than phosphorus due to
electron repulsion
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