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chemical changes
electrolysis
electrolysis of aluminium oxide
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Cards (17)
Why are metals more reactive than carbon extracted using electrolysis?
They cannot be
reduced
by carbon
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What is the compound used to extract aluminium?
Aluminium oxide
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What is the purpose of mixing aluminium oxide with cryolite?
To lower the
melting point
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What is the melting point of aluminium oxide?
Around
2000° C
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What materials are the cathode and anode made of in the electrolysis setup?
Graphite
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Why is graphite used for electrodes in electrolysis?
It conducts
electricity
and has a high
melting point
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What happens to aluminium ions at the cathode?
They gain
electrons
to form aluminium atoms
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What is the half equation for the reaction at the cathode?
A
l
3
+
+
Al^{3+} +
A
l
3
+
+
3
e
−
→
A
l
3e^- \rightarrow Al
3
e
−
→
A
l
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What happens to oxide ions at the anode?
They lose
electrons
to form oxygen atoms
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What is the half equation for the reaction at the anode?
O
2
−
→
1
2
O
2
+
O^{2-} \rightarrow \frac{1}{2}O_2 +
O
2
−
→
2
1
O
2
+
2
e
−
2e^-
2
e
−
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What do the oxygen atoms formed at the anode do?
They pair up to form
oxygen molecules
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Why must the anode be replaced regularly?
It reacts with
oxygen
to form
carbon dioxide
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What are the two reasons why producing metals by electrolysis is expensive?
High energy for
melting
and
electric current
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What is the process of extracting aluminium by electrolysis?
Mix
aluminium oxide
with
cryolite
Apply electric current to molten mixture
Aluminium ions
move to cathode,
gain
electrons
Oxide ions move to
anode
,
lose
electrons
Oxygen atoms form and
pair
up
to O2
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What are the key reactions occurring during the electrolysis of aluminium oxide?
At the
cathode
:
A
l
3
+
+
Al^{3+} +
A
l
3
+
+
3
e
−
→
A
l
3e^- \rightarrow Al
3
e
−
→
A
l
(
reduction
)
At the
anode
:
O
2
−
→
1
2
O
2
+
O^{2-} \rightarrow \frac{1}{2}O_2 +
O
2
−
→
2
1
O
2
+
2
e
−
2e^-
2
e
−
(
oxidation
)
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What are the properties of graphite that make it suitable for electrodes in electrolysis?
Good conductor of electricity
High melting point
Stable at high temperatures
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What is the significance of the melting point in the electrolysis process?
Lower
melting point
reduces
energy costs
Allows
easier
handling of materials
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