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Cards (22)

  • What does it mean when a reaction is at equilibrium?
    The rate of forward and reverse reactions are equal
  • What are the methods that can be used to measure equilibrium?
    • Measure change in colour using colorimeter
    • Use pH probe
    • Measure electrical conductivity
    • Titration for slow equilibrium changes
  • What does mole fraction mean?
    The amount of a given component in a mixture
  • Write the equation used to calculate mole fraction.
    Mole fraction = moles of A / total moles
  • What does partial pressure mean?
    The pressure exerted by a single species
  • What is the symbol for partial pressure?
    P
  • Write the equation used to calculate partial pressure.
    Partial pressure = mole fraction x total pressure
  • What is the relationship between concentration of a substance and its partial pressure?
    Concentration is proportional to partial pressure
  • What are the 3 common units of pressure used in chemistry?
    • Pascals
    • Atmospheres
    • Newtons per square metre
  • What type of brackets are used in Kc expressions?
    Square brackets
  • What type of brackets are used in Kp expressions?
    Round brackets
  • How do you calculate Kp for the reaction aA (g) + bB (g) ⇌ cC (g) + dD (g)?
    Kp = (PC)c(PD)d(PA)a(PB)b\frac{(P_C)^c (P_D)^d}{(P_A)^a (P_B)^b}
  • How do you calculate the units for Kp?
    Write units for partial pressures and cancel
  • What is the symbol of equilibrium constant?
    K
  • What does it mean when K is greater than 1?
    Reaction favours products
  • What does it mean when K is less than 1?
    Reaction favours reactants
  • What is the effect of increasing temperature on K?
    Equilibrium shifts to endothermic direction
  • What is the effect of decreasing temperature on K?
    Equilibrium shifts to exothermic direction
  • What is the effect of increasing temperature on K for a forward endothermic reaction?
    K increases as temperature increases
  • What is the only factor that affects K?
    Temperature
  • What effect does a catalyst have on K?
    Catalysts do not affect the position of equilibrium
  • What is the effect of increasing temperature on K for a forward exothermic reaction?
    K decreases as temperature increases