strong electrostatic forces of attraction between a shared pair of elecrons and positively charged nuclei of the atom
the greater the number of shared pairs of electrons the greater the attraction between the two covalently bonded atoms
an incomplete octet are only in group...
2 and 13
electronegativity
The tendency of an atom in a molecule to attract the shared pair of electrons towards itself
bond polarity
the distribution of electric charge across a chemical bond between two atoms
covalent bond due to electrostatic attraction of nuclei to bond electrons
intermolecular forces
refer to the attractive forces between 2 or more molecules
ex. hydrogen bonds, dipole-dipole forces
intramolecular forces
the attractive forces within a molecule or compound
ex. the covalent bond, the ionic bond
covalent network structure
consist of a lattice of atoms all covalently bonded together to form essentially one giant molecule held together by very strong covalent bonds
allotrope
one or more forms of a chemical element that can exist in the same physical state
polyatomic ions
Ions made up of more than one atom, which have become charged due to the overall loss or gain of electrons
Ionic bonding is the bonding that occurs when two oppositely charged ions experience an electrostatic attraction towards one another.
The larger the lattice enthalpy the stronger the ionic bond
properties of metals
Lustre (shiny appearance)
Sonority (sound when struck)
Malleability (can be reshaped on compression)
Ductility (can be drawn out into a wire)
Electrical conductivity
Thermal conductivity
A metallic bond is a bond resulting from attractions between positive ions and surrounding mobile electrons
The smaller the radius of the metal ion, the stronger the metallic bond. This is because of the shorter distance between the positive nucleus of the cation and the surrounding delocalised electrons.
semi-conductor is a material that has an electrical conductivity value falling between that of a conductor
isoelectronic ions
atoms, ions or molecules that have some electronic structure and same number of valence electrons
halogens
group 17
noble gas
group 18
amphoteric
able to react both as a base and acid
lattice
a 3-dimensioned repeating structure made up of particles held by together by very strong interactions
ionization energy
the enthalpy change when an electron is removed from one mole of an atom in the gaseous state
isolated atom
noble gas
lattice enthalpy
the energy required to form one mole of an ionic compound from its ions in their gaseous state
electron affinity
the enthalpy change when an electron is added to an isolated atom in the gaseous state
anions of elements on their own always end in -ide
the greater the number of shared pairs of electrons the greater the attraction between the two covalently bonded atoms
the non-bonding electrons exert more repulsion than bonding electron pairs
Diamond
each carbon atom is covalently bonded tetrahedrally to four other carbon atoms
diamond has a rigid structure, with no plane of weakness. This makes it one of the hardest naturally occurring substances
diamond is used as a cutting tool in drill tips
in the diamond, all four elements in each carbon atom has been used for covalent bonding. it has no free electrons and not conduct electricity
graphite
each carbon atom is covalently bonded in a trigonal planar arrangement to three other carbon atoms to form hexagonal layers
graphite
the layers are held together by weak intermolecular forces of attraction between the layers which contain delocalised electrons
graphite is a good lubricant and has a waxy feel as the layers can slide each other
graphite is a good conductor of electricity as there are delocalised electrons that can move through the layers
graphite is soft
graphite has high melting and boiling point
buckminsterfullerene
each molecule of buckminsterfullerene consist of sixty carbon atoms, and it is not a true covalent network structure