the energy required to remove an electron from an one mole atom in the gaseous state (to form one mole of gaseous 1+ ions) kJ mol^-1
Periodicity
a repeating pattern of properties
Electron affinity
the enthalpy change when an electron is added to an atom in the gaseous state (exothermic process)
Lattice enthalpy
the energy required to form one mole of an ionic compound from its ions in their gaseous state
Isoelectronic ions
atoms, ions or molecules that have the same electronic structure and same number of valence electrons
Electronegativity
a measure of the tendency of an atom to attract a bonding pair of electrons
Isolated atom
a group of atoms that exists separately without any bonding with other atoms= Noble gases
The ionic bond
an electrostatic force between positive and negative ions
Lattice
a 3-dimensioned repeating structure made up of particles held together by very strong interactions
shielding effect
the decrease in the force of attraction exerted by the nucleus on the valence electrons due to the presence of electrons in the inner shells
Ligands
Lewis bases with a lone pair of electrons that they can donate to a central metal ion
Isotopes
elements that have same number of protons but different number of neutrons
Amphoteric
a compound able to react both as a base and as an acid
valence electrons
the electrons in the outermost shell, or energy level, of an atom
amphiprotic
a proton-bearing molecule that is capable of donating its proton as well as accepting an additional proton
octet
the eight-electron arrangement in the outer electron shell of the noble-gas atoms
actinides
a series of metallic elements whose atomic numbers start from 89 and end at 103
isoelectronic ions
ions that have the same number of electrons
atomic radius
The distance from an atom's nucleus to the outermost orbital of one of its electrons. Usually measured as the half-distance between the nuclei of two of the same atoms bonded together
effective nuclear charge
the net positive charge pulling these electrons towards the nucleus
when there is an energy level difference between two positive ions that are not in the same group, the Zeff plays more important rule
decrease ionization energy when element increase energy level because electrons are further away from the nucleus, and there is less effective nuclear charge
generally absolute values of electron affinity increase across a period and decrease down a group
it is easier to remove an electron from paired sub-level than from non-paired sub-level because two electrons are repealing.
elements are arranged into four blocks - s,p,d,f
periods are numbered according to the outermost energy level (n) that is occupied by electrons
the number of the principal energy level (n) and the number of the valence electrons in an atom can be deduced from its position on the periodic table
elements are arranged in horizontal rows called periods
elements are arranged in 18 vertical columns called groups
group number refers to the valence electrons of the element