A type of polymerization reaction where monomers are continuously added to the growing polymer chain.
Monomers
Small molecules that are added to the growing polymer chain during addition polymerization.
Polypropene
A type of polymer made by the addition polymerization of the monomer propene.
Properties of polypropene
Strong fibers, tough, easily molded and colored, high elasticity.
Macaroni string necklace analogy
A comparison to the process of making a macaroni string necklace, where monomers are added to form a chain like adding pasta to a string.
Double C=C bond
A bond found in alkene molecules that breaks open during addition polymerization.
Addition polymerization of alkene molecules
The double C=C bond breaks open to form a -C-C- bond, and monomers are added to the end of the growing chain until no more monomers are left.
Condensation reaction
A reaction where twomoleculescombine with the loss of a smallmolecule, such as water, to form a newcompound.
Esters
A family of chemicals formed by the condensation reaction between carboxylic acids and alcohols.
Functional group –COOC-
The characteristic functional group of esters, formed by the reaction of –COH and –COOH parts.
Ethane diol
A diol used in the production of polyesters.
Polyester
A polymer formed by the condensation reaction between ethane diol and hexanedioic acid.
Polymer formation
Molecules with different functional groups react together to form very long molecules, often in solution and at low temperatures.
Functional groups
The reactive parts of molecules that participate in polymer formation.
Condensation Polymerization Advantages
Wider range of monomers: no need for C=C double bond, Lower temperature and pressure: gentler conditions, Easy separation: solid forms are easy to isolate.
Disadvantages of Condensation Polymerization
Lower atom economy: forms water as a byproduct, reduces efficiency; More expensive starting materials: original molecules used in the reaction can be pricier than those used in addition polymerization.
Examples of Naturally Occurring Fibres
Wool, silk, and linen (flax)
Basis of Natural Fibres
Proteins: silk and wool | Cellulose: linen and cotton | Starch: carbohydrates
Monomer
Amino acids, Sugars (Monosaccharides), Cellulose
Polymer
Proteins, Starch, Cellulose
Polymerization
Molecules with different functional groups react together at low temperature in solution, producing a polymer and often a small molecule (water, etc.)