London dispersion forces

Cards (7)

  • Permanent dipoles can induce dipoles in non-polar molecules by pulling / pushing the electrons across the other molecule
  • As electron density fluctuates at all times, if the electron density ever becomes unsymmetrical, an instantaneous dipole will be generated
  • The end where the electron density increases will have a δ\delta - charge
  • The δ\delta + will attract electrons from another molecule, and the δ\delta - will repel electrons from another molecule, moving the electron density, creating an induced dipole in the other molecule
  • The induced dipole will always be aligned so the interaction with the instantaneous dipole is favourable
  • London forces are the weakest type of Van der Waals forces, but the attractive force is stronger with more electrons
  • All molecules (polar and non-polar) will experience instantaneous dipoles caused by the movement of electrons