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Module 5 Physical chemistry and transition elements
18 Rates of reaction
18.1 Orders, rate equations and rate constants
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Jayden Clauer
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Rate of reaction
is the change of
concentration
of a
reactant
or a product in a given amount of time
Orders
show how rate is affected by
concentration
If a substance has
zero order
, the rate is not affected by
concentration
If a substance has
first order
, the rate changes by the same factor as the concentration change
If a substance has
second order
, the
rate
changes by the same factor as the
concentration
range raised to the power 2
Overall order
of a reaction is the sum of the individual order of the
reactants
The
rate equation
shows the link between rate, concentration and
orders
The
rate constant
k
is the proportionality constant in the rate equation
In the
rate equation
, the
concentration
of the reactants are raised to the
power
of their
order
The
rate equation
can be rearranged to find the value of
k