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Module 5 Physical chemistry and transition elements
20 Acids, bases and pH
20.3 The acid dissociation constant Ka
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In
aqueous
solutions,
strong acids
completely
dissociate
In
aqueous
solutions,
weak acids
partially
dissociate
The
acid dissociation constant
Ka
is the equilibrium constant that measures the extent of acid dissociation
Ka
= (
[H+]
[A-])/
[HA]
The larger the value of
Ka
, the greater the dissociation and the
stronger
the acid
pKa
= -
log(Ka)
Ka
= 10^-
pKa
The stronger the
acid
, the larger the
Ka
value and the smaller the
pKa
value
The weaker the
acid
, the smaller the
Ka
value and the larger the
pKa
value