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Chemistry AQA
Mechanisms
Nucleophilic substitution
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Haloalkane to nitrile
The halogen goes through nucleophilic substitution to produce a
nitrile
( e.g chloropropane would turn to
butanenitrile
)
It requires a
CN-
ion (
cyanide
)
In
ethanolic
conditions
Reagents is
KCN
Halogenalkanes to alcohol
Halogenalkanes go through
nucleophilic substitution
to produce an alcohol
It needs OH- ions
Warm
and
aqueous
conditions
Reactant is
NaOH
Halogenalkanes to 1°amine
Halogenalkanes go through nucleophilic substitution to form 1°amime
They require an
excess
of
ammonia
(
NH3
)
In
ethanol
Haloalkane to 2°/3° amines and 4° alkyl ammonium salt
Haloalkanes go through
nucleophilic substitution
to form 2°/3° amines and 4° alkyl ammonium salt.
They require an
excess
of haloalkanes
In
ethanoic
conditions
Reagents
is 1°,2°, 3° amines