aromatic compounds

Cards (89)

  • Who is the presenter of the video on aromatic compounds?
    Chris Harris
  • What is the main focus of the video?
    To review OCR A aromatic compounds
  • For which exam board is the video specifically designed?
    OCR A
  • What is the purpose of the video for students?
    To review content or learn new material
  • Are the videos available for free?
    Yes, they are completely free
  • What does the presenter ask viewers to do to show support?
    Subscribe to the channel
  • What can viewers purchase related to the video content?
    A private copy of the slides
  • Why is exam technique important according to the presenter?
    It helps in answering exam questions effectively
  • What specific content does the video cover regarding benzene?
    Benzene electrophilic substitution
  • What is the molecular formula of benzene?
    C<sub>6</sub>H<sub>6</sub>
  • How are the carbon atoms in benzene bonded?
    Each carbon is bonded to two other carbons
  • What is the bond length of carbon-carbon bonds in benzene?
    139 picometers
  • Why do all carbon-carbon bonds in benzene have the same length?
    Due to delocalized electrons
  • How does the stability of benzene compare to cyclohexene?
    Benzene is more stable than cyclohexene
  • What is the enthalpy change of hydrogenation for cyclohexene?
    -120 kilojoules per mole
  • What would be the expected enthalpy change of hydrogenation for benzene if it had three double bonds?
    -360 kilojoules per mole
  • What is the actual enthalpy change of hydrogenation for benzene?
    -208 kilojoules per mole
  • What does a lower enthalpy value indicate about benzene's stability?
    Benzene is more stable than expected
  • What is a 'wings' in chemistry?
    A substance with a benzene ring
  • How are substituents named on a benzene ring?
    By numbering the carbons to give lowest numbers
  • What is phenol?
    A benzene ring with an -OH group
  • What is the reaction type when bromine is added to an alkene?
    Electrophilic addition
  • What happens to bromine water when added to an alkene?
    It changes color from brown to colorless
  • What is an electrophile?
    An electron-loving species
  • What does the presence of a double bond in alkenes indicate?
    High electron density
  • How does bromine behave when approaching a double bond?
    It becomes polarized due to electron repulsion
  • What happens to electrons in a double bond when bromine approaches?
    They move to one side of the molecule
  • What is the role of bromine in the reaction described?
    Bromine acts as the electrophile
  • What is an electrophile?
    An electron-loving species that attacks electron-rich areas
  • What does bromine add to in the reaction?
    It adds to the alkene
  • How does bromine become polarized when approaching a double bond?
    Electrons in the double bond repel and shift
  • What happens to the bromine-bromine bond during the reaction?
    The bromine-bromine bond breaks
  • What type of intermediate is formed after bromine adds to the alkene?
    A carbocation intermediate is formed
  • What ion is produced when the bromine-bromine bond breaks?
    A BR minus ion is produced
  • What is the result of the reaction between the carbocation and BR minus?
    A colorless compound is formed
  • What is the difference between electrophilic addition and electrophilic substitution reactions?
    • Electrophilic addition: Electrophile adds to a double bond
    • Electrophilic substitution: Electrophile replaces a hydrogen in a stable ring
  • What type of reaction do alkenes undergo?
    Electrophilic addition reactions
  • Why do benzene rings undergo electrophilic substitution instead of addition?
    To maintain stability of the delocalized electrons
  • What are the two mechanisms for electrophilic substitution in benzene?
    Friedel-Crafts acylation and nitration
  • What is the role of the halogen carrier in Friedel-Crafts acylation?
    It produces a stronger electrophile