thermodynamics

Cards (114)

  • What is the definition of enthalpy change of formation?
    Change when one mole of compound forms
  • What is lattice enthalpy of formation?
    Change when solid ionic compound forms from ions
  • What is the lattice enthalpy of dissociation?
    Change when solid ionic compound dissociates into ions
  • What does the enthalpy change of dissociation refer to?
    Breaking one mole of bonds in gaseous state
  • What is the enthalpy change of first ionization?
    Change when gaseous atoms form gaseous ions
  • What is enthalpy change of atomization?
    Change when gaseous atoms form from elements
  • What is the second ionization energy?
    Change when gaseous two-plus ions form from one-plus ions
  • What is the first electron affinity?
    Change when one mole of gaseous ions form from atoms
  • What is the second electron affinity?
    Change when gaseous two-minus ions form from one-minus ions
  • Why are Born-Haber cycles useful?
    To calculate lattice enthalpies indirectly
  • What is the starting point of a Born-Haber cycle for lithium chloride?
    Solid lithium chloride
  • What is the enthalpy of atomization of chlorine in the cycle?
    Converts 12Cl2\frac{1}{2}Cl_2 gas to Cl gas
  • What is the first ionization energy of lithium?
    Removal of an electron to form lithium ion
  • What happens during the electron affinity step for chlorine?
    Chlorine gains an electron, releasing energy
  • What is the lattice enthalpy of formation in the cycle?
    Formation of lithium chloride from gaseous ions
  • How does the Born-Haber cycle relate to Hess's law?
    Enthalpy change is independent of the route taken
  • What is the significance of the direction of arrows in the Born-Haber cycle?
    Indicates whether the process is endothermic or exothermic
  • What is the relationship between endothermic and exothermic processes in the cycle?
    Endothermic processes require energy input
  • How do you calculate lattice enthalpies using the Born-Haber cycle?
    By applying known values to the cycle
  • What is the enthalpy of atomization value for chlorine in the cycle?
    Divided by two for Cl2Cl_2 gas
  • What is the significance of the lattice enthalpy of formation value?
    Indicates stability of the ionic compound
  • What does a negative lattice enthalpy value indicate?
    Exothermic formation of the ionic compound
  • What does a positive lattice enthalpy value indicate?
    Endothermic process for ionic compound formation
  • How does the Born-Haber cycle help in understanding ionic compounds?
    It illustrates energy changes during formation
  • What is the role of energy in the Born-Haber cycle?
    Energy is required for endothermic steps
  • What is the importance of practicing Born-Haber cycles?
    To become familiar with definitions and processes
  • What is the relationship between the Born-Haber cycle and thermodynamics?
    It applies thermodynamic principles to ionic compounds
  • How can students effectively learn the definitions related to thermodynamics?
    By integrating them into practical examples
  • What is the significance of the enthalpy change in the Born-Haber cycle?
    It quantifies energy changes in reactions
  • What is the purpose of the video on AQA thermodynamics?
    To clarify thermodynamic concepts for students
  • What is the expected outcome of watching the AQA thermodynamics video?
    Improved understanding of thermodynamic principles
  • What is the relationship between the definitions and the Born-Haber cycle?
    Definitions are applied within the cycle
  • How does the video aim to simplify complex chemistry topics?
    By breaking down concepts into manageable parts
  • What is the significance of the standard states in thermodynamics?
    They provide a reference for enthalpy changes
  • What is the role of the AQA specifications in the video?
    To ensure all relevant topics are covered
  • What is the expected benefit of subscribing to the A Lurie chemistry channel?
    Access to more educational chemistry content
  • What is the importance of practicing with the Born-Haber cycle?
    To reinforce understanding of thermodynamic concepts
  • How does the video help students with exam preparation?
    By providing targeted information for AQA exams
  • What is the significance of the definitions in thermodynamics?
    They are essential for understanding concepts
  • How does the video address common student difficulties in chemistry?
    By simplifying complex topics and definitions