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thermodynamics
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Cards (114)
What is the definition of enthalpy change of formation?
Change when
one mole
of compound forms
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What is lattice enthalpy of formation?
Change when solid
ionic compound
forms from ions
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What is the lattice enthalpy of dissociation?
Change when solid
ionic compound
dissociates into ions
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What does the enthalpy change of dissociation refer to?
Breaking
one mole
of bonds in
gaseous state
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What is the enthalpy change of first ionization?
Change when
gaseous
atoms form gaseous ions
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What is enthalpy change of atomization?
Change when gaseous atoms form from
elements
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What is the second ionization energy?
Change when
gaseous
two-plus
ions form from
one-plus
ions
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What is the first electron affinity?
Change when
one mole
of
gaseous
ions form from atoms
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What is the second electron
affinity?
Change when
gaseous
two-minus
ions form from
one-minus
ions
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Why are Born-Haber cycles useful?
To calculate
lattice enthalpies
indirectly
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What is the starting point of a Born-Haber cycle for lithium chloride?
Solid
lithium
chloride
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What is the enthalpy of atomization of chlorine in the cycle?
Converts
1
2
C
l
2
\frac{1}{2}Cl_2
2
1
C
l
2
gas to Cl gas
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What is the first ionization energy of lithium?
Removal of an
electron
to form lithium ion
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What happens during the electron affinity step for chlorine?
Chlorine gains an electron, releasing
energy
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What is the lattice enthalpy of formation in the cycle?
Formation
of
lithium chloride
from
gaseous
ions
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How does the Born-Haber cycle relate to Hess's law?
Enthalpy change
is independent of the route taken
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What is the significance of the direction of arrows in the Born-Haber cycle?
Indicates whether the process is
endothermic
or
exothermic
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What is the relationship between endothermic and exothermic processes in the cycle?
Endothermic processes require
energy input
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How do you calculate lattice enthalpies using the Born-Haber cycle?
By applying
known values
to the cycle
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What is the enthalpy of atomization value for chlorine in the cycle?
Divided by two for
C
l
2
Cl_2
C
l
2
gas
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What is the significance of the lattice enthalpy of formation value?
Indicates stability of the
ionic compound
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What does a negative lattice enthalpy value indicate?
Exothermic
formation of the ionic compound
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What does a positive lattice enthalpy value indicate?
Endothermic
process for ionic compound formation
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How does the Born-Haber cycle help in understanding ionic compounds?
It illustrates
energy changes
during formation
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What is the role of energy in the Born-Haber cycle?
Energy is required for
endothermic
steps
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What is the importance of practicing Born-Haber cycles?
To become familiar with
definitions
and processes
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What is the relationship between the Born-Haber cycle and thermodynamics?
It applies thermodynamic principles to
ionic compounds
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How can students effectively learn the definitions related to thermodynamics?
By integrating them into
practical
examples
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What is the significance of the enthalpy change in the Born-Haber cycle?
It quantifies
energy changes
in reactions
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What is the purpose of the video on AQA thermodynamics?
To clarify thermodynamic concepts for students
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What is the expected outcome of watching the AQA thermodynamics video?
Improved understanding of thermodynamic principles
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What is the relationship between the definitions and the Born-Haber cycle?
Definitions
are
applied
within
the
cycle
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How does the video aim to simplify complex chemistry topics?
By breaking down
concepts
into manageable parts
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What is the significance of the standard states in thermodynamics?
They provide a reference for
enthalpy changes
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What is the role of the AQA specifications in the video?
To ensure all relevant
topics
are covered
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What is the expected benefit of subscribing to the A Lurie chemistry channel?
Access to more educational chemistry content
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What is the importance of practicing with the Born-Haber cycle?
To reinforce understanding of
thermodynamic
concepts
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How does the video help students with exam preparation?
By providing targeted information for
AQA
exams
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What is the significance of the definitions in thermodynamics?
They are essential for understanding
concepts
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How does the video address common student difficulties in chemistry?
By simplifying complex
topics
and
definitions
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