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chemistry a level
Module 5
5.1
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Cards (82)
What is the relationship between the concentration of NO2 and the temperature (1/T) shown in the graph?
As the temperature (1/T) increases, the concentration of NO2 decreases.
The graph shows an
inverse relationship
between NO2 concentration and temperature.
What is the pre-exponential factor in the Arrhenius equation represented by?
A
How does the concept of the pre-exponential factor help in understanding chemical kinetics?
It provides insight into
collision frequency
How does a lower activation energy (Ea) influence reaction speed?
It makes reactions happen
faster
What is the chemical reaction represented in the image?
2NO2 →
2NO
+
O2
What is the relationship between temperature and reaction rate?
Higher temperature increases reaction rate
Particles
move faster and collide more
Similar to shaking a box of toys
How do you plug values into the Arrhenius equation?
Use
k
=
k =
k
=
A
∗
A *
A
∗
e
−
E
a
/
(
R
∗
T
)
e^{ - Ea / (R * T)}
e
−
E
a
/
(
R
∗
T
)
What does the pre-exponential factor help us understand?
How fast a
chemical reaction
is happening
What does 'R' represent in the Arrhenius equation?
Gas constant
(
8.314 J/mol·K
)
In what fields is the Arrhenius equation used?
Cooking
, chemistry, and material science
What does 'Ea' stand for in the Arrhenius equation?
Activation energy
What does the pre-exponential factor indicate?
Frequency
of collisions in a reaction
What is the gradient of the line produced by ln(k) vs 1/T?
-
Ea/R
How does temperature (T) affect the reaction rate according to the Arrhenius equation?
It influences
collision frequency
and
activation energy
What does a larger pre-exponential factor imply about particle movement?
Particles are moving and
colliding
more
What does 'A' represent in the Arrhenius equation?
Pre-exponential factor
If the temperature is 0.00165 K^-1, what is the approximate concentration of NO2?
1.5
mol/L
How does increasing temperature affect the cooking of an egg?
It
cooks
the
egg
faster
How does shaking a box of toys relate to chemical reactions?
More shaking increases
particle collisions
How does the pre-exponential factor relate to chemical reaction speed?
It indicates how fast
reactions
occur
How does temperature affect the rate constant according to the Arrhenius equation?
Increasing
temperature
increases
the rate constant
What are the units of the activation energy (Ea)?
J/mol
What happens to particles in a chemical reaction as temperature increases?
They move faster and
collide
more
What is the role of the gas constant (R) in the Arrhenius equation?
Converts between energy units and temperature
What does the rate constant indicate in a chemical reaction?
How fast the reaction
occurs
What is the value of the gas constant (R)?
8.314
J/mol·K
What is the first step in solving problems using the Arrhenius equation?
Identify given values:
Ea
, A,
T
,
R
What is the activation energy (Ea) in the context of the Arrhenius equation?
The energy required to start a
reaction
What does the Arrhenius equation reveal about reaction rates at higher temperatures?
Faster
reaction
rates
at
higher
temperatures
What are the four key components of the Arrhenius equation?
A:
Pre-exponential factor
Ea:
Activation energy
(J/mol)
R:
Gas constant
(
8.314
J/mol·K)
T:
Temperature
(K)
If given
A
=
A =
A
=
5.0
×
1
0
12
s
−
1
5.0 \times 10^{12} s^{ - 1}
5.0
×
1
0
12
s
−
1
,
E
a
=
Ea =
E
a
=
150
k
J
/
m
o
l
150 kJ / mol
150
k
J
/
m
o
l
, and
T
=
T =
T
=
300
K
300 K
300
K
, what is the first step to calculate k?
Convert Ea to J/mol
What are the key components of the Arrhenius equation and their significance?
Pre-exponential factor
(A): Frequency of collisions; higher A = faster reactions
Activation energy
(Ea): Minimum energy for reaction; lower Ea = faster reactions
Gas constant
(R): Converts energy units and temperature
Temperature
(T): Influences collision frequency; higher T = faster rate constant
What does the pre-exponential factor (A) represent in the Arrhenius equation?
Frequency of collisions between
reacting particles
If the pre-exponential factor is low, what can be inferred about the reaction rate?
The
reaction rate
is likely
slow
What is activation energy?
Minimum energy needed for a
reaction
What does the Arrhenius equation describe?
Relationship between
reaction rate
and
temperature
How does the number of toys in a box affect their collisions when shaken?
More
toys lead to more collisions
What is the overall effect of increasing temperature on chemical reactions?
It increases the rate of chemical reactions
What is activation energy (
E
a
E_a
E
a
) in the context of the Arrhenius equation?
Energy needed for
particles
to react
What does the Arrhenius equation describe?
Relationship between
rate constant
and
temperature
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