Cells get energy from glucose. Plats store excess glucose.
Starch is a mixture of two alpha-glucose molecules - amylose and amylopectin.
Amylose is a long, unbranched chain of alpha-glucose. The angles of the glycosidic bonds give it a coiled structure, almost like a cylinder. This makes it compact, so it is really good for structure because you can fit more into a small space.
Amylopectin is a long, branched chain of alpha-glucose. Its side branches allow the enzymes that break down the molecule to get at the glycosidic bonds easily. This means that glucose can be released quickly.
Starch is insoluble in water, so it doesn't cause water to enter the cells by osmosis which would make them swell. This makes it good for storage.