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Chemistry
Topic 17: Organic chem II
carboxylic acids
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Cards (12)
have a
carboxyl
functional group
-
COOH
suffix
is -ioc
carboxyl
group made of a
carbonyl
group and a
hydroxyl
group
carboxyl group
is always at the end of the
molecule
carboxylic acids
can form
hydrogen bonds
some can dissolve in
water
as the
carbon chain
increases the solubility of the
carboxylic acid
decreases
this is because the longer
hydrocarbon
components are non-polar therefore cant form hydrogen bonds
dimer
when a
carboxylic acid
forms
hydrogen bonds
with each other
this increases the
boiling point
Carboxylic acids
can be made from
nitriles
,
aldehydes
and
primary alcohols
Hydrolysis
of
nitriles
forms
carboxylic acids
Oxidation of
aldehyde
and primary alcohols using
reducing agents
form
carboxylic acids
Carboxylic acids are weak acids that react with carbonates to form carbon dioxide and bases to form salts and water
Carboxylic acids
can be reduced into
alcohols
which can be reacted to form
acyl chlorides
Reacting alcohols with carboxylic acid and acid anhydride to form esters