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AS Chemistry Unit 2
Alcohols
Introduction
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The general formula of alcohols is
Cn H2n+1 OH.
The functional group in alcohols is the
polar hydroxy group
(
O-H
).
A secondary alcohol has
2 alkyl
groups attached to the
carbon
atom that is attached to the
OH
group.
A primary alcohol has
1 alkyl
group attached to the
carbon
atom that is attached to the
OH
group.
A tertiary alcohol has
3 alkyl
groups attached to the
carbon
atom that is attached to the
OH
group.
Structural isomerism occurs in
alcohols
when
3
carbon
atoms
are reached.
In alcohols, the
longest chain
must contain the
OH group.
The
hydroxy
(
OH
) group is polar due to the
electronegativity difference
between the
oxygen
and
hydrogen
atoms.
The
polarity
of the
hydroxy
group leads to a
permanent
dipole
and so
hydrogen
bonding
occurs between
alcohol
molecules.