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AS chemistry
1.7 oxidation,reduction and redox reactions
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Cards (46)
Reduction
and
oxidation
involve the
transfer
of
electrons.
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The acronym OIL RIG stands for
oxidation
is the
loss
of electrons,
reduction
is the
gain
of electrons.
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In a
redox
reaction, one element is
oxidized
and another element is
reduced.
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Calcium
is being
oxidized
in the reaction because it's
losing
electrons, forming Ca
2+.
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Oxygen is being
reduced
in the reaction as it's
gaining
electrons, forming
OH-.
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Calcium combined with
oxygen
forms
Ca 2+.
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When calcium combines with
oxygen
, it forms
Ca 2+
because it's
losing electrons.
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When
oxygen
combines with
calcium
, it forms
OH-
because it's
gaining electrons.
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Group
two
elements are always
oxidation
state of plus
two.
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The most electronegative element takes priority in terms of
oxidation state.
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Oxygen
is oxidation state of
minus two
except in
peroxide
where it's
minus one
and in Oh F - where it's plus
two.
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Uncombined
elements always have an
oxidation
number of
zero.
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Fluorine is always
oxidation
state of
minus one.
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Group
one
elements are always
oxidation
state of plus
one.
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Group
three
elements are always
oxidation
state of plus
three.
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Hydrogen
is always
oxidation
state of plus
one
except in
hydrides
where it's
minus
one.
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Each
element
can be assigned an
oxidation number
, which depends on a
set
of
rules.
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Ions have an
oxidation
number that is the same as the
charge
on the ion.
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Reducing agents
lose
electrons and
oxidize
themselves.
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In the reaction, calcium is the
reducing
agent as it's
losing
electrons.
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Oxidizing
agents
gain
electrons and are themselves
reduced.
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In the reaction,
oxygen
is the
oxidizing
agent as it's
accepting
electrons.
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In NaCl, sodium is
+1
and chlorine is
-1
, so the reaction is
oxidation.
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Peroxide has an oxidation number of
-1
because it contains
one
oxygen atom.
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Oxygen is
-2
in
peroxide
because it has
four hydrogens
attached.
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In
Fe3O4
, iron is
+3
because the oxidation number of oxygen is
-2.
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In
Fe2O3
, both ions are
+6
because the oxidation number of oxygen is
-2.
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In VO2, vanadium is
+4
because the oxidation number of oxygen is
-2.
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In FeO, iron is
+3
because the oxidation number of oxygen is
-2.
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In V2O3, vanadium is
+4
because the oxidation number of oxygen is
-2.
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In
SO2
,
sulfur
is +
6
because it is the most
electronegative
element.
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In V2O5, vanadium is
+5
because the oxidation number of oxygen is
-2.
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In SO4 2-, sulfur is
+6
because it has a charge of
-2.
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In H2SO4, oxygen is
-2
because it is the most
electronegative
element.
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In the reaction
MnO4- MN2+
, the species before and after are
written down
, and the atoms apart from
oxygen
and
hydrogen
are
balanced.
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In a half equation, any atoms apart from
oxygen
and
hydrogen
are
balanced
,
oxygens
are
balanced
with
water
,
hydrogens
are
balanced
with
H+
ions, and
charges
are
balanced
with
electrons.
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Sodium ethoxide
increases
in oxidation number and chlorine
decreases
in oxidation number, resulting in a
reduction.
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The total charge on the reaction
MnO4- MN2+
must be
zero
, and this is achieved by
balancing electrons.
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The
oxygens
in the reaction
MnO4- MN2+
are
balanced
with
water
, and the
hydrogens
are
balanced
with
H+
ions.
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The
total charge
on a
half
equation must be
zero
, and this is achieved by
balancing electrons.
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