Phosphorus pentoxide (P4O10) and sulfur dioxide (SO2) form simple molecular structures and their melting points are lower due to the weak intermolecular forces holding them together.
The melting points of Group III oxides vary, with sodium oxide having a lower melting point than magnesium oxide due to the larger charge on the magnesium ions.
Silicon dioxide forms giant covalent structures and requires loads of energy to break these, making it insoluble in water and reacting with a base to form a salt.