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Chemistry
1B
Kinetics
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Erin Daly
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Kinetics
The study of the rate of chemical reactions
What does the rate normally depend on? How can it be investigated?
The
concentration
of the
reactants,
it can only be
investigated
experimentally
How is concentration represented?
Concentration
of
A
is represented as [
A
] and
similar
for
B
What is the order of a reaction?
The
different effects
reactants have on
rate.
We determine this through
experiments
What are orders of reaction used for?
To relate the
rafe
of a
reaction
to the
reacting species
Zero order
When changing [A] has
no effect
in
rate
(w.r.t. A)
First order
When doubling [A]
doubles rate
(w.r.t. A)
Second order
When
doubling
[
A
]
increases
rate
fourfold
(w.r.t.
A
)
The
order
of a
reaction
with
respect
to any
one reactant
is the
power
to which the
concentration
of that
reactant
is
raised
in the
rate equation
What is k?
The
rate constant
(a
constant
which takes account of the
effect
of other factors such as
surface area
,
temperature
etc
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