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General Chemistry
Electron Configurations
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Electron
Configurations
= distributing e- among
atomic
orbitals
Ground
state configuration =
LOWEST
energy
In
Hydrogen
or
1 e-
systems (Bohr) - ALL
orbitals
in a
shell
have the
SAME
energy
=
n
ONLY
s,p,d,f subshells:
SAME energy
in a 1
ELECTRON
atom = energy based on
ELECTRON
interactions with the
NUCLEUS
and
OTHER ELECTRONS
Pauli Exclusion Principle
= no more than
2 ELECTRONS
per
ORBITAL
Aufbau principle
= fill
lowest ENERGY
orbital first; s<p<d<f
Hund's Rule
=
FILL
up all available
ORBITALS
first BEFORE pairing
electrons
= Most stable arrangement for e- =
degenerate
, # of e- are
MAXIMIZED
Core
electrons =
Noble Gases
representing
inner
electrons
Valance electrons =
outermost
electrons with the
HIGHEST
n
Same # of
valance
electrons = same
chemical properties
Paramagnetic
= elements with
different
#s of +1/2 and -1/2 electrons
One
type of
spin
over the
other
attracted to a
magnet
Diamagnetic
= species with the
same
#s of +1/2 and -1/2 electrons
NOT attracted to a magnet