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A Levels
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Group 7
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Cards (21)
Fluorine
Colour
Yellow
gas
Chlorine
Colour
Green
gas
Bromine
Colour
Orange
/
Brown
liquid
Iodine
Colour
Grey solid
Boiling Points as you go down the group
Increase
because the
strength
of the
Van der Waals increases
with the
atomic radius
Electronegativity
as you go
down
the group
Decreases
as
distance
from the
nucleus
and
shielding increase
Reducing power
of
ions
as you go
down
the
group
Increases
as the
distance
from the
nucleus
and
shielding increase
making it
easier
for an
electron
to be
lost
Fluoride
with
silver nitrate
No precipitate
Chloride
with
silver nitrate
White Precipitate
Bromide
with
silver nitrate
Cream Precipitate
Iodide
with
silver nitrate
Yellow Precipitate
Silver Chloride
with
ammonia
white precipitate dissolves
in
dilute ammonia
Silver bromide
with
ammonia
cream precipitate dissolves
in
concentrated ammonia
Silver iodide
with
ammonia
yellow precipitate insoluble
in
concentrated ammonia
Oxidising
power down the group
Decreases
down the group, as there is an
increase
in
shielding
,
weakening
the
attraction
to
outer electrons.
KCl + H2SO4 =
HCl
+
KHSO4 Acid-Base
reaction
KBr
+
H2SO4
=
Br2.
+.
SO2 Redox
KI + H2SO4 =
I2
+
H2S
(
rotten egg smell
),
purple burst REDOX
Cl2
+
H2O
<=> in the
dark
HClO
(
chloric
(
1
)
acid
) +
HCl Kills microbs
^
2Cl2
+
2H2O
= in
sunlight
4HCl
+
O2.
(
No HClO
!)
What is used to clean swimming pool water?
NaClO
(
salt
of
HClO
) The
ph
of
swimming pools
must
not drop
to
acidic
, or
Cl2
will
come out
of
solution