nucleophilic addition

Cards (4)

  • -CN cyanide ion (form nitriles) has a triple bond
  • when aldehydes or ketones react with cyanide ion, they form hydroxynitriles (contain an OH group and CN group). reacts in aqueous solution with sulfuric acid
  • nucleophilic addition
    • negatively charged cyanide ion attracted to partially positive carbon atom
    • very similar to reduction of aldehydes and ketones
  • naming hydroxynitriles
    1. carbon in the nitrile is position one in the carbon chain
    2. follow naming conventions as normal