REACTIONS OF METAL OXIDES

Cards (4)

  • REACTIONS OF BASIC METAL OXIDES AND WATER?
    Na2O (s) + H2O (l) -> 2Na+ (aq) + 2OH- (aq)
    • strongly alkaline solution formed
    • pH 14
    MgO (s) + H2O (l) -> Mg(OH)2 (s) ⇋ Mg (2+) (aq) + 2OH- (aq)
    • sparingly soluble in water
    • somewhat alkaline solution formed
    • pH 9
    WHY DOES IT OCCUR?
    • O (2-) ion
    • is a strong base
    • attracts H+
    • readily react to produce OH-
    • but MgO less alkaline solution as it is less soluble
  • REACTIONS OF INSOLUBLE METAL OXIDES AND WATER?
    • Al2O3 no reaction as bonding too strong to separate ions
    • SiO2 no reaction as it is giant macromolecule
  • REACTIONS OF ACIDIC METAL OXIDES AND WATER?
    P4O10 (s) + 6H2O (l) -> 4H3PO4 (l)
    H3PO4 (aq) ⇋ H+ (aq) + H2PO4- (aq)
    • phosphorus pentoxide reacts violently with water
    • produces phosphoric acid solution
    • which then ionises
    SO2 (g) + H2O (l) -> H2SO3 (aq)
    H2SO3 (aq) ⇋ H+ (aq) + HSO3- (aq)
    • fairly soluble
    • produces sulfuric (IV) acid solution
    • which then partially dissociates
    SO3 (g) + H2O (l) -> H2SO4 (aq) -> H+ (aq) + HSO4- (aq)
    • reactions violently
    • produces sulfuric (VI) acid solution
  • REACTIONS WITH ACIDS AND ALKALIS?
    Na2O
    • reacts with acids to produce salt and water
    MgO
    • reacts with acids to produce salt and water
    Al2O3
    • amphoteric
    • reacts with both acids and alkalis
    SiO2
    • reacts with weak acids as a strong base
    • e.g. SiO2 (s) + CaO (l) -> CaSiO3 (l)
    P4O10
    • reacts with alkali in multiple stages
    • e.g. 3NaOH (aq) + H3PO4 (aq) -> Na3PO4 (aq) + 3H2O (l)
    SO2
    • reacts with alkali if itself is an aqueous solution
    • also reacts to remove flue gases (CaO (s) + SO2 (g) -> CaSO3 (s))