An example of volunteer sampling is putting up a poster at school asking for participants to self-select and take part in your research. You have to imagine green sweets are the most helpful and willing to take part, followed by yellow. The orange, red and purple sweets definitely won't want to take part. You are still looking to recruit 25 participants but if you can't manage to get to 25 you will still have to run your experiment with as many as you can.