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Chemistry
Reactions of Ions in Aqueous Solutions
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Created by
Preet Dukhi
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Cards (55)
Who is the presenter of the video on reactions of ions in aqueous solutions?
Chris Harris
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What type of ions does the video focus on?
Transition metal ions
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What is the main focus of the video?
Reactions of
transition metal ions
in water
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What educational level is the video designed for?
AQA
A level
chemistry
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What type of information does the video avoid?
Generic
information
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Where can viewers find more revision videos related to AQA chemistry?
AQA
or
Malory
chemistry
YouTube
channel
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What is the purpose of the slides mentioned in the video?
To aid in
revision notes
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What happens to metal aqua complexes when they are formed?
They are surrounded by six
water ligands
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What type of bond is formed between water ligands and metal ions?
Coordinate bonds
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What is the significance of the charge on metal aqua ions?
It affects their
acidity
in solution
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What happens when iron two plus ions are dissolved in water?
They form a
complex
with
six
water ligands
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What does the formation of H3O+ indicate about a solution?
The solution is
acidic
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How does the acidity of Fe3+ complexes compare to Fe2+ complexes?
Fe3+
complexes are more
acidic
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What is hydrolysis in the context of metal aqua complexes?
Breaking part of the complex using
water
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What is the effect of charge density on metal ions?
Higher charge density increases
acidity
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Why are three plus metal ions more polarizing than two plus ions?
They have a higher
charge density
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What happens when hydroxide ions are added to metal aqua ions?
They form
insoluble metal hydroxides
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What is the result of adding more hydroxide ions to a metal aqua complex?
It
shifts
the
equilibrium
to the right
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What happens to the charge of a complex when it becomes neutral?
It becomes
insoluble
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What is the significance of a precipitate forming in a reaction?
It indicates the formation of an
insoluble compound
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How does the process of hydrolysis relate to acid-base equilibrium?
It involves shifting equilibrium with
H3O+
ions
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What happens to the charge of a complex when it becomes neutral?
It becomes solid and
insoluble
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Why does a neutral complex form a precipitate?
Because it becomes
insoluble
in solution
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How many hydroxides are needed for a metal with a +3 charge?
Three
hydroxides
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What is the process of hydrolysis in metal hydroxides?
It involves the reaction with
water
to form
complexes
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How does hydrolysis differ between +2 and +3 metal ions?
+3 ions require
three
steps
, +2 ions require
two
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What does amphoteric mean in the context of metal hydroxides?
They can act as both
acids
and
bases
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What happens when an acid is added to an amphoteric metal hydroxide?
It dissolves by accepting
protons
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How does aluminium hydroxide behave when a base is added?
It acts as a
Bronsted-Lowry acid
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What is produced when aluminium hydroxide reacts with a base?
Aluminium hydroxide
complex and water
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What occurs when excess ammonia is added to metal aqua ions?
It can lead to
ligand exchange reactions
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How does the addition of small amounts of ammonia compare to hydroxide addition?
Both produce the same
metal hydroxides
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What happens when excess ammonia is added to copper ions?
Some
ligands
are displaced, forming a soluble complex
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What distinguishes the reaction of +2 and +3 metal ions with carbonates?
+
2
ions
form
carbonates
,
+3
ions
do
not
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What is produced when a +3 metal ion reacts with a carbonate?
Hydroxide
complex, carbon dioxide, and water
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How can you test if a solution contains a +3 metal ion?
Add
carbonate
and check for fizzing
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What indicates a +2 metal ion when reacting with carbonate?
No
fizzing
occurs
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What type of carbonate is produced with a 2 plus metal ion?
Methyl carbonate
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What is formed when a 3 plus metal ion reacts with carbonate?
Hydroxide complex
,
carbon dioxide
, and water
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How can you distinguish between a 2 plus and a 3 plus metal ion using carbonate?
Fizzing indicates a
3
plus ion
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