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Chemistry 162
Test 1: Frequency, Wavelength, Electronegativity, etc.
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M
=
x10^6
k
=
x10^3
d
=
10^-1
n
=
x10^-9
c
=
x10^-2
m
=
x10^-3
µ =
x10^-6
The properties of
radiation
are described by
three
parameters:
Wavelength
Frequency
Amplitude
wavelength
(λ), or
distance
between two successive
peaks
frequency
(ν) is the
number
of
waves
that pass through a
point
per
second.
amplitude
(A) is the
maximum displacement
from
equilibrium
position to either
side
of it.
Electromagnetic spectrum
- all forms of
electromagnetic
radiation arranged according to
wavelength
or
frequency
Visible
light has a range of wavelengths from about
400
nm to
750
nm
Infrared
radiation has
longer
wavelength than
visible
light but
shorter
wavelength than
radio
waves
Ultraviolet
light has
shorter
wavelength than
visible
light but
longer
than
X-ray
X-ray
has very
short
wavelength compared with
ultraviolet
light
Gamma
ray has even
smaller
wavelength than
x-ray
Radio waves
have very
long
wavelengths compared with other types of
EM
radiation
X-ray
has
short
wavelengths compared with
visible
light
speed of light =
C
=
3.00
x
10
^
8
m/s
C
=
λv
V
=
c
/
λ
E
=
hc
/
λ
h =
6.626
x
10
^
-23
J/s-1
Quantized states
-
discrete energy levels
Continum
states - smooth
transition
between levels
work
=
φ
KE =
hc
-
φ
φ (
work
) is either
gained
or
absorbed
Rydberg Equation
:
λ
= [
R
(
1/n1
^2 -
1/n2
^2)]^
-1
R =
1.1
x
10
^
7
m-1
KE =
hc
/
λ-φ
n1 is always
smaller
than n2
Paschen (
infared
wavelengths):
n=3
Balmer (
visible
wavelengths):
n=2
Luman (
ultraviolet
wavelengths):
n=1
Ground state
energy is
closest
to the nucleus
Excited states
occur
between
states due to
emission
or
absorbtion
of energy
Bohr Energy (
hydrogen
atom): E =
k
/
n^2
k =
Rhc
(
-2.179
x 10^
-18
J)
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