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Topic 18: Organic Chemistry III
18.1 Amines
18.1.1 Structure and Nomenclature
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What are amines derived from?
Ammonia
What is the defining feature of primary amines?
One H replaced
Tertiary amines have all three hydrogen atoms in ammonia replaced by alkyl or
aryl
groups.
True
Match the type of amine with its general formula:
Primary amine ↔️ R-NH₂
Secondary amine ↔️ R₂NH
Tertiary amine ↔️ R₃N
Trimethylamine ((CH₃)₃N) is an example of a
tertiary
amine.
What is the general formula for secondary amines?
R₂NH
What happens to the hydrogen atoms in ammonia to form tertiary amines?
All three are replaced
How many hydrogen atoms in ammonia are replaced in a primary amine?
One
Trimethylamine is an example of a
tertiary
amine
What are alkyl groups derived from?
Alkanes
What is the difference between straight-chain and branched alkyl groups?
Linear vs. branched carbon chains
What is the general formula for amines?
Depends on the type
Primary amines have the general formula
R-NH₂
What is the notation for an ethyl group?
C₂H₅
Isopropyl is a branched form of the
propyl
group
What is the notation for a propyl group?
C₃H₇
Branched alkyl groups have
carbon atoms
branching off the main chain.
True
Give an example of a branched alkyl group.
Isopropyl
What is the IUPAC name for CH₃-NH₂?
Methylamine
When naming secondary amines, the two alkyl group names are listed in
alphabetical
order.
What is the IUPAC name for (CH₃)₂NH?
Dimethylamine
What is the IUPAC name for (CH₃)₃N?
Trimethylamine
Cyclic amines are named using IUPAC nomenclature by combining the name of the ring with the suffix
-amine
.
Match the cyclic amine with its IUPAC name:
Pyrrolidine ↔️ Pyrrolidine
Piperidine ↔️ Piperidine
When naming amines with multiple functional groups, the
priority
of functional groups must be considered.
True
The IUPAC name for CH₃-CH₂-NH-CH₂-COOH is 3-Aminopropanoic
acid
.
Amines are formed when hydrogen atoms in ammonia are replaced by alkyl or
aryl
groups.
True
The general formula for primary amines is
R-NH₂
What is the defining feature of secondary amines?
Two H replaced
In primary amines, one hydrogen atom of ammonia is replaced by an alkyl or
aryl
group.
Give an example of a primary amine.
CH₃-NH₂
The general formula for primary amines is R₃N.
False
Methylamine (CH₃-NH₂) is an example of a
primary
amine.
The general formula for a primary amine is
R-NH₂
Secondary amines have the general formula
R₂NH
True
Match the type of amine with its general formula:
Primary ↔️ R-NH₂
Secondary ↔️ R₂NH
Tertiary ↔️ R₃N
The alkyl group with the formula CH₃ is called
methyl
Match the alkyl group with its notation:
Methyl ↔️ CH₃
Ethyl ↔️ C₂H₅
Propyl ↔️ C₃H₇
Tertiary amines have all three hydrogen atoms of ammonia replaced.
True
Match the type of amine with its example:
Primary ↔️ Methylamine
Secondary ↔️ Dimethylamine
Tertiary ↔️ Trimethylamine
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