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AP Chemistry
Unit 9: Thermodynamics and Electrochemistry
9.6 Galvanic (Voltaic) and Electrolytic Cells
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Galvanic cells convert the chemical energy of a spontaneous redox reaction into electrical
energy
Steps in the operation of a galvanic cell:
1️⃣ Oxidation occurs at the anode
2️⃣ Reduction occurs at the cathode
3️⃣ Electrons flow through external circuit
4️⃣ Ions flow through salt bridge
In an electrolytic cell, the anode is positively
charged
Galvanic cells require an external voltage to function.
False
In a Galvanic Cell, the redox reaction is
spontaneous
In an Electrolytic Cell, the energy conversion is from electrical to
chemical
Match the cell type with its characteristic:
Galvanic Cell ↔️ Spontaneous redox reaction
Electrolytic Cell ↔️ Non-spontaneous redox reaction
The salt bridge in a Galvanic Cell allows electrons to flow between half-cells.
False
What is the charge of the anode in an Electrolytic Cell?
Positive
Match the cell type with its energy conversion:
Galvanic Cell ↔️ Chemical to Electrical
Electrolytic Cell ↔️ Electrical to Chemical
In a galvanic cell, the anode is negatively
charged
Electrolytic cells convert chemical energy into electrical energy.
False
Galvanic cells convert chemical energy into electrical
energy
The anode in a Galvanic Cell is positively charged.
False
The cathode in an Electrolytic Cell is positively charged.
False
What is the role of the salt bridge in a Galvanic Cell?
Maintain electrical neutrality
What is another name for a Galvanic Cell?
Voltaic Cell
An Electrolytic Cell requires an external voltage to operate.
True
What is the charge of the cathode in a Galvanic Cell?
Positive
What type of energy conversion occurs in a Galvanic Cell?
Chemical to electrical
Galvanic cells use a salt bridge to maintain electrical
neutrality
Steps in the operation of a Galvanic Cell
1️⃣ Oxidation occurs at the anode.
2️⃣ Electrons flow through an external circuit.
3️⃣ Reduction occurs at the cathode.
4️⃣ Salt bridge maintains electrical neutrality.
In cell notation, the anode is written on the
left
Electrochemical devices convert the chemical energy of a spontaneous redox reaction into
electrical
Galvanic cells, also called voltaic cells, use a spontaneous redox reaction to generate
electrical
Electrolytic cells convert electrical energy into
chemical
What is the charge of the anode in a galvanic cell?
Negative
What is the role of the salt bridge in a galvanic cell?
Balance charge
Order the components of a cell notation from left to right:
1️⃣ Anode
2️⃣ Anode Electrolyte
3️⃣ Salt Bridge
4️⃣ Cathode Electrolyte
5️⃣ Cathode
What is the sign of
Δ
G
\Delta G
Δ
G
for a nonspontaneous reaction?
Positive
The salt bridge in a galvanic cell is represented by
||
.
True
What is the value of
Δ
G
\Delta G
Δ
G
for a non-spontaneous reaction?
Δ
G
>
0
\Delta G > 0
Δ
G
>
0
Galvanic cells convert chemical energy into
electrical
The cathode in a galvanic cell has a
positive
What is the charge of the anode in an electrolytic cell?
Positive
In a Galvanic Cell, the spontaneous redox reaction generates an electrical
current
Galvanic cells consist of two key components: electrodes and a
salt bridge
.
True
What is the role of the salt bridge in a Galvanic Cell?
Maintains electrical neutrality
Cell notation begins with the anode and ends with the
cathode
.
True
A reaction is spontaneous if
Δ
G
\Delta G
Δ
G
is negative.
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