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AP Chemistry
Unit 2: Compound Structure and Properties
2.5 Lewis Diagrams
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Lewis diagrams depict the bonding between atoms and the lone pairs of
electrons
Match the exception to the octet rule with its description:
Odd Electron Species ↔️ Molecules with an odd number of valence electrons
Electron Deficient Species ↔️ Central atoms lack enough electrons
Expanded Octet Species ↔️ Central atoms exceed 8 valence electrons
Hydrogen and helium only require 2
valence electrons
to satisfy their stability
True
CO₂ forms double bonds between carbon and each oxygen atom to satisfy the octet rule
True
What is an example of an odd electron species?
NO
What type of bonds are present in the Lewis diagram of CO₂?
Double bonds
What is the definition of the octet rule?
Atoms form compounds with 8 valence electrons
Match the exception type with its example:
Odd electron species ↔️ NO
Electron deficient species ↔️ BF₃
Expanded octet species ↔️ SF₆
In NaCl, sodium forms a Na⁺ cation by losing one valence
electron
to chlorine.
True
In covalent compounds, atoms can be connected using single, double, or triple
bonds
In the octet rule, each atom must have
8
valence electrons, except for hydrogen which needs 2.
What is an example of an electron deficient species?
BF₃
Match the concept with its significance:
Valence electron arrangement ↔️ Determines bonding and reactivity
Bonding between atoms ↔️ Influences molecular shape and stability
Lone pairs ↔️ Affects molecular geometry and reactivity
When drawing Lewis diagrams, maximize the number of
covalent
bonds using the remaining valence electrons.
Expanded octet species occur because central atoms in period 3 and beyond can use available
d
orbitals.
Match the exception type with its example:
Odd electron species ↔️ ClO₂
Electron deficient species ↔️ AlCl₃
Expanded octet species ↔️ SF₆
What does the octet rule state in chemistry?
Atoms achieve 8 valence electrons
What is the first rule for drawing Lewis diagrams?
Determine valence electrons
Atoms in period 3 and beyond can accommodate more than 8 valence electrons due to available
d
orbitals.
Sulfur (S) can have 10 or 12 valence electrons in a compound because it has an expanded valence
shell
.
Match the exception to the octet rule with its example:
Odd Electron Species ↔️ NO
Electron Deficient Species ↔️ BF₃
Expanded Octet Species ↔️ SF₆
Electron-deficient species such as BF₃ lack a complete
octet
The first step in drawing a Lewis diagram is to determine the total number of valence
electrons
Hydrogen and helium only need 2 valence electrons to achieve
stability
.
True
What is the primary difference between Lewis diagrams for ionic and covalent compounds?
Complete electron transfer
Steps for drawing Lewis diagrams for ionic compounds
1️⃣ Determine the ions formed
2️⃣ Draw individual ion structures
3️⃣ Use brackets and charges
What do Lewis diagrams for covalent compounds show?
Valence electrons and bonding
Molecules with an odd number of valence electrons can satisfy the octet rule for all atoms.
False
Lewis diagrams are a type of Lewis structure that only depicts
valence electrons
.
True
Expanded octet species
are an exception to the octet rule.
True
In a Lewis diagram, all atoms must have exactly 8 valence electrons to satisfy the octet rule
False
What is the primary goal of the octet rule?
Stable electron configuration
How many valence electrons does CO₂ have?
16
The Lewis diagram for CO₂ shows double bonds between carbon and each
oxygen
atom.
Expanded octet species can have more than 8 valence electrons around the central atom.
True
Steps for drawing Lewis diagrams
1️⃣ Determine the total number of valence electrons
2️⃣ Arrange the atoms
3️⃣ Add lone pairs
4️⃣ Maximize the number of covalent bonds
5️⃣ Satisfy the octet rule
Exceptions to the octet rule include atoms that can be stable with fewer or more than 8 valence
electrons
In ionic compounds, ions are enclosed in brackets and their
charges
are indicated.
What do Lewis diagrams for covalent compounds show?
Arrangement of valence electrons
Key steps for drawing Lewis diagrams
1️⃣ Determine the total number of valence electrons
2️⃣ Arrange the atoms and form bonds
3️⃣ Add lone pairs
4️⃣ Satisfy the octet rule
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