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3.3 Organic Chemistry
3.3.10 Aromatic Chemistry (A-level only)
3.3.10.1 Structure of Benzene
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The molecular formula of benzene is
C₆H₆
Benzene's unique structure features alternating single and double bonds within a ring, creating a highly stable conjugated
system
Benzene's planar ring with alternating single and
double
bonds contributes to its high stability.
True
Match the cyclic hydrocarbon with its bonding and stability.
Benzene ↔️ Conjugated π system, High stability
Cyclohexene ↔️ One double bond, Less stable
Cyclohexane ↔️ All single bonds, Least stable
In benzene, the electrons from the alternating single and double bonds are spread evenly across the entire ring, forming a stable
conjugated
system.
Benzene is a planar, cyclic hydrocarbon molecule with the chemical formula
C₆H₆
.
Benzene has six carbon atoms and six hydrogen atoms arranged in a planar ring structure with alternating single and double
bonds
.
The Kekulé structure of benzene depicts alternating single and double bonds within the six-membered
ring
.
The resonance hybrid of benzene represents the molecule as an average of two Kekulé structures with π electrons delocalized across the entire
ring
.
Benzene is a planar, cyclic hydrocarbon
molecule
with alternating single and double bonds.
True
Order the following cyclic hydrocarbons based on their bonding and stability, from highest to lowest stability.
1️⃣ Benzene
2️⃣ Cyclohexene
3️⃣ Cyclohexane
The Kekulé structure of benzene depicts it as a planar, cyclic hydrocarbon with alternating single and double
bonds
Delocalization in
benzene
refers to the spreading of electrons across the entire ring.
True
Benzene has stronger delocalization and higher stability compared to cyclohexane.
True
Cyclohexane is less stable than benzene because it lacks a
conjugated
π system.
True
Benzene's conjugated π system makes it more stable than alkenes with isolated double bonds.
True
The Kekulé structure of benzene explains its high stability due to delocalized
π electrons
.
True
The resonance hybrid structure of benzene increases its stability compared to
localized
single and double bonds.
True
What is the arrangement of carbon and hydrogen atoms in benzene?
Planar ring
What does the molecular formula C₆H₆ indicate about benzene?
Six carbon and hydrogen atoms
How does the stability of benzene compare to cyclohexene in the Kekulé structure?
Benzene is more stable
What is the effect of delocalization on the stability of benzene?
Enhances its stability
Match the compound with its delocalization and stability:
Benzene ↔️ Strong delocalization, high stability
Cyclohexene ↔️ Weak delocalization, lower stability
Cyclohexane ↔️ No delocalization, lowest stability
Match the compound with its properties:
Benzene ↔️ C₆H₆, planar ring with conjugated π system
Cyclohexene ↔️ C₆H₁₀, cyclic ring with one double bond
Cyclohexane ↔️ C₆H₁₂, cyclic ring with all single bonds
Match the compound with its bonding and stability:
Benzene ↔️ Conjugated π system, high stability
Cyclohexene ↔️ One double bond, less stable
Cyclohexane ↔️ All single bonds, least stable
Order the compounds based on their delocalization and stability from highest to lowest:
1️⃣ Benzene
2️⃣ Cyclohexene
3️⃣ Cyclohexane
Match the property with the correct compound:
Benzene ↔️ Planar, cyclic ring with conjugated π system
Alkenes ↔️ Open-chain molecules with one double bond